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Author | dc.contributor.author | Bunton, C. A. | |
Author | dc.contributor.author | Robinson, L. | |
Author | dc.contributor.author | Sepulveda, L. | |
Admission date | dc.date.accessioned | 2018-12-20T15:04:42Z | |
Available date | dc.date.available | 2018-12-20T15:04:42Z | |
Publication date | dc.date.issued | 1970 | |
Cita de ítem | dc.identifier.citation | Journal of Organic Chemistry, Volumen 35, Issue 1, 2018, Pages 108-114 | |
Identifier | dc.identifier.issn | 15206904 | |
Identifier | dc.identifier.issn | 00223263 | |
Identifier | dc.identifier.other | 10.1021/jo00826a024 | |
Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/157602 | |
Abstract | dc.description.abstract | The catalytic efficiencies of phenyl- and 2,4-dimethoxyphenylcetyldimethylammonium bromides (CPDA and CDPDA) are greater than that of cetyltrimethylammonium bromide (CTABr) for the spontaneous hydrolyses of the dianions of 2,4- and 2,6-dinitrophenyl phosphates, the reactions of hydroxide and fluoride ions with p-nitrophenyl diphenyl phosphate, and the reaction of hydroxide ion with 2,4-dinitrochlorobenzene in water, because of more efficient micelle-substrate binding. There is little effect upon the rate in the micellar phase. 2,4-DimethoxybenzyIcetyldimethylammonium bromide (CDBDA) is an even better catalyst for the spontaneous hydrolysis of 2,4-dinitrophenyl phosphate, but not for the other reactions, probably because of its low solubility in water. © 1970, American Chemical Society. All rights reserved. | |
Lenguage | dc.language.iso | en | |
Type of license | dc.rights | Attribution-NonCommercial-NoDerivs 3.0 Chile | |
Link to License | dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/cl/ | |
Source | dc.source | Journal of Organic Chemistry | |
Keywords | dc.subject | Organic Chemistry | |
Título | dc.title | Structural Effects upon Catalysis by Cationic Micelles | |
Document type | dc.type | Artículo de revista | |
Cataloguer | uchile.catalogador | SCOPUS | |
Indexation | uchile.index | Artículo de publicación SCOPUS | |
uchile.cosecha | uchile.cosecha | SI | |
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