Oxidation of 3,5-ditert-butylcatechol catalyzed by copper(II) complexes. A kinetic study
| Author | dc.contributor.author | Manzur Saffie, Jorge | |
| Author | dc.contributor.author | Garcia, A. M. | |
| Author | dc.contributor.author | Rivas, V. | |
| Author | dc.contributor.author | Atria Salas, Ana María | |
| Author | dc.contributor.author | Valenzuela, J. | |
| Author | dc.contributor.author | Spodine Spiridonova, Evgenia | |
| Admission date | dc.date.accessioned | 2018-12-20T15:04:43Z | |
| Available date | dc.date.available | 2018-12-20T15:04:43Z | |
| Publication date | dc.date.issued | 1997 | |
| Cita de ítem | dc.identifier.citation | Polyhedron, Volumen 16, Issue 13, 2018, Pages 2299-2305 | |
| Identifier | dc.identifier.issn | 02775387 | |
| Identifier | dc.identifier.other | 10.1016/S0277-5387(96)00528-1 | |
| Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/157605 | |
| Abstract | dc.description.abstract | Copper(II) complexes of the ligands (6-methyl-2,2′-dipyridyl)methane (MeDPM) and (6,6′-dimethyl-2,2′-dipyridyl)methane (diMeDPM) were prepared and used as catalysts for the oxidation of 3,5-ditert-butylcatechol to 3,5-ditert-butyl-o-benzoquinone. The rate of reaction was determined in the presence and absence of base (KOH) in methanol. The kinetic data are interpretated, postulating two reactive species towards molecular oxygen: a copper(I) complex and a species described as a ternary copper(II) catecholate complex. © 1997 Elsevier Science Ltd. | |
| Lenguage | dc.language.iso | en | |
| Publisher | dc.publisher | Elsevier Ltd | |
| Type of license | dc.rights | Attribution-NonCommercial-NoDerivs 3.0 Chile | |
| Link to License | dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/cl/ | |
| Source | dc.source | Polyhedron | |
| Keywords | dc.subject | 3,5-ditert-butylcatechol | |
| Keywords | dc.subject | Catalysis | |
| Keywords | dc.subject | Copper(II) complexes | |
| Keywords | dc.subject | Dioxygen | |
| Keywords | dc.subject | Kinetics | |
| Keywords | dc.subject | Oxidation | |
| Título | dc.title | Oxidation of 3,5-ditert-butylcatechol catalyzed by copper(II) complexes. A kinetic study | |
| Document type | dc.type | Artículo de revista | |
| Cataloguer | uchile.catalogador | SCOPUS | |
| Indexation | uchile.index | Artículo de publicación SCOPUS | |
| uchile.cosecha | uchile.cosecha | SI |
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Except where otherwise noted, this item's license is described as Attribution-NonCommercial-NoDerivs 3.0 Chile