Reaction of tris(1,10-phenanthroline) cobalt(III) perchlorate, nitromethane and an excess of base-I reaction with pyridine
| Author | dc.contributor.author | Baraona, Ruth | |
| Author | dc.contributor.author | Rozenblum, Sylvia | |
| Author | dc.contributor.author | Zamudio, Walter | |
| Admission date | dc.date.accessioned | 2018-12-20T15:10:03Z | |
| Available date | dc.date.available | 2018-12-20T15:10:03Z | |
| Publication date | dc.date.issued | 1978 | |
| Cita de ítem | dc.identifier.citation | Journal of Inorganic and Nuclear Chemistry, Volumen 40, Issue 12, 2018, Pages 2043-2047 | |
| Identifier | dc.identifier.issn | 00221902 | |
| Identifier | dc.identifier.other | 10.1016/0022-1902(78)80200-0 | |
| Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/158120 | |
| Abstract | dc.description.abstract | Kinetic studies of the [Co(phen)3] (ClO4)3 2H2O nitromethane pyridine reaction were made spectrophotometrically, by recording the appearance of a new absorption band at 474 nm. The reaction is first order with respect to all three reactants. Reaction products were isolated and attempts were made to purify them. A mechanism is proposed for the reaction involving the formation of Co(phen)33+CH2NO2- (ClO4)2. The rate determining step would be the rupture of a CH bond in the solvated nitromethane molecule. © 1978. | |
| Lenguage | dc.language.iso | en | |
| Type of license | dc.rights | Attribution-NonCommercial-NoDerivs 3.0 Chile | |
| Link to License | dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/cl/ | |
| Source | dc.source | Journal of Inorganic and Nuclear Chemistry | |
| Título | dc.title | Reaction of tris(1,10-phenanthroline) cobalt(III) perchlorate, nitromethane and an excess of base-I reaction with pyridine | |
| Document type | dc.type | Artículo de revista | |
| Cataloguer | uchile.catalogador | SCOPUS | |
| Indexation | uchile.index | Artículo de publicación SCOPUS | |
| uchile.cosecha | uchile.cosecha | SI |
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