Quinoa protein extracts (Q) were prepared and alkalised at pH 8 and 12 (Q-8 and Q-12). Qs were mixed with chitosan (CH) to form Q/CH mixtures. The optimal proportion of the mixtures was determined by the formation of coacervates. All the films were obtained by solution casting. From the optimal Q/CH mixture and the addition of three different concentrations of sunflower oil (SO) 2.9, 3.8 and 4.7 g/100 mL, and the optimal proportion of SO g/100 mL was selected based on the mechanical and barrier properties of the films. The CH, Q/CH and Q/CH/SO optimal blend films were characterised by FTIR, X-ray diffraction, and SEM. The physicochemical properties of the films were also evaluated. The 0.1 Q-8/CH blend was selected due to its high degree of interaction between the quinoa proteins and CH. The optimum concentration of SO used in the Q-8/CH/SO film was 2.9 g/100 mL. The addition of SO to the film improved the water-vapour permeability (WVP) as a result of hydrophobic interactions and the