Author | dc.contributor.author | Atria Salas, Ana María | |
Author | dc.contributor.author | Garland, María Teresa | |
Author | dc.contributor.author | Baggio, Ricardo | |
Admission date | dc.date.accessioned | 2018-12-20T15:11:01Z | |
Available date | dc.date.available | 2018-12-20T15:11:01Z | |
Publication date | dc.date.issued | 2015 | |
Cita de ítem | dc.identifier.citation | Acta Crystallographica Section C: Structural Chemistry, Volumen 71, | |
Identifier | dc.identifier.issn | 20532296 | |
Identifier | dc.identifier.other | 10.1107/S2053229615004751 | |
Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/158356 | |
Abstract | dc.description.abstract | © 2015 International Union of Crystallography.Three isotypic rare earth complexes, catena-poly[[aquabis(but-2-enoato-κ2 O,O')yttrium(III)]-bis(μ-but-2-enoato)-κ3 O,O':O;κ3 O:O,O'-[aquabis(but-2-enoato-κ2 O,O')yttrium(III)]-μ-4,4'-(ethane-1,2-diyl)dipyridine-κ2 N:N'], [Y2(C4H5O2)6(C12H12N2)(H2O)2], the gadolinium(III) analogue, [Gd2(C4H5O2)6(C12H12N2)(H2O)2], and the gadolinium(III) analogue with a 4,4'-(ethene-1,2-diyl)dipyridine bridging ligand, [Gd2(C4H5O2)6(C12H10N2)(H2O)2], are one-dimensional coordination polymers made up of centrosymmetric dinuclear [M(but-2-enoato)3(H2O)]2 units (M = rare earth), further bridged by centrosymmetric 4,4'-(ethane-1,2-diyl)dipyridine or 4,4'-(ethene-1,2-diyl)dipyridine spacers into sets of chains parallel to the [20 ] direction. There are intra-chain and inter-chain hydrogen bonds in the structures, the former providing cohesion of the linear arrays and the latter promoting the formation of broad planes parallel to (010). | |
Lenguage | dc.language.iso | en | |
Publisher | dc.publisher | International Union of Crystallography | |
Type of license | dc.rights | Attribution-NonCommercial-NoDerivs 3.0 Chile | |
Link to License | dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/cl/ | |
Source | dc.source | Acta Crystallographica Section C: Structural Chemistry | |
Keywords | dc.subject | 4,4'-(ethane-1,2-diyl)dipyridine | |
Keywords | dc.subject | 4,4'-(ethene-1,2-diyl)dipyridine | |
Keywords | dc.subject | but-2-enoate | |
Keywords | dc.subject | crystal structure | |
Keywords | dc.subject | gadolinium(III) complexes | |
Keywords | dc.subject | isotypic rare earth complexes | |
Keywords | dc.subject | one-dimensional coordination polymers | |
Keywords | dc.subject | yttrium(II) complexes | |
Título | dc.title | Three isotypic polymeric complexes with rare earth cations, but-2-enoate anions and 4,4'-(ethane-1,2-diyl)dipyridine and 4,4'-(ethene-1,2-diyl)dipyridine bridging ligands | |
Document type | dc.type | Artículo de revista | |
Cataloguer | uchile.catalogador | SCOPUS | |
Indexation | uchile.index | Artículo de publicación SCOPUS | |
uchile.cosecha | uchile.cosecha | SI | |