Cyclic voltammetry and electron paramagnetic resonance study of the electrochemical reduction of p-nitrobenzyl bromidel in aprotic solvents
| Author | dc.contributor.author | Norambuena, E. | |
| Author | dc.contributor.author | Olea, C. | |
| Author | dc.contributor.author | Aliaga, C. | |
| Admission date | dc.date.accessioned | 2018-12-20T15:13:10Z | |
| Available date | dc.date.available | 2018-12-20T15:13:10Z | |
| Publication date | dc.date.issued | 1993 | |
| Cita de ítem | dc.identifier.citation | Spectroscopy Letters, Volumen 26, Issue 8, 2018, Pages 1547-1557 | |
| Identifier | dc.identifier.issn | 15322289 | |
| Identifier | dc.identifier.issn | 00387010 | |
| Identifier | dc.identifier.other | 10.1080/00387019308011633 | |
| Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/158528 | |
| Abstract | dc.description.abstract | EPR has been used to investigate the radicals postulated as intermediates in the intramolecular electron transfer and dehalogenation of p-nitrobenzyl bromide (p-NBBr) in DMSO and DMFA at room temperature. The electrochemical behavior has been studied through the use of cyclic voltammetry. According to the postulated reaction mechanism, the one-electron reduction of p-nitrobenzyl bromide generates an anion radical which undergoes breakage of the C-Br bond followed by. © 1993, Taylor & Francis Group, LLC. All rights reserved. | |
| Lenguage | dc.language.iso | en | |
| Type of license | dc.rights | Attribution-NonCommercial-NoDerivs 3.0 Chile | |
| Link to License | dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/cl/ | |
| Source | dc.source | Spectroscopy Letters | |
| Keywords | dc.subject | aprotic solvents | |
| Keywords | dc.subject | electrochemical reduction | |
| Keywords | dc.subject | electron-transfer | |
| Keywords | dc.subject | EPR | |
| Keywords | dc.subject | KEY NORDS | |
| Keywords | dc.subject | Nitro radical | |
| Título | dc.title | Cyclic voltammetry and electron paramagnetic resonance study of the electrochemical reduction of p-nitrobenzyl bromidel in aprotic solvents | |
| Document type | dc.type | Artículo de revista | |
| Cataloguer | uchile.catalogador | SCOPUS | |
| Indexation | uchile.index | Artículo de publicación SCOPUS | |
| uchile.cosecha | uchile.cosecha | SI |
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Except where otherwise noted, this item's license is described as Attribution-NonCommercial-NoDerivs 3.0 Chile