Reactivity of [Mo(NHNPH2)(NNPH2)Br2(acac)] toward di-imines. X-ray crystal structure of [Mo(NNPH2)2Br2(o-phen)]
| Author | dc.contributor.author | Bustos, Carlos | |
| Author | dc.contributor.author | Matamala, Marcia | |
| Author | dc.contributor.author | Boys, Daphne | |
| Author | dc.contributor.author | Carrillo, David | |
| Admission date | dc.date.accessioned | 2018-12-20T15:20:36Z | |
| Available date | dc.date.available | 2018-12-20T15:20:36Z | |
| Publication date | dc.date.issued | 2002 | |
| Cita de ítem | dc.identifier.citation | Boletin de la Sociedad Chilena de Quimica, Volumen 47, Issue 4, 2018, Pages 557-561 | |
| Identifier | dc.identifier.issn | 03661644 | |
| Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/158837 | |
| Abstract | dc.description.abstract | Complex [Mo(NHNPh2)(NNPh2)Br2(acac)], acac=acetylacetonate, reacts in acetonitrile with 1,10-phenanthroline, o-phen, and 2,2′-bipyridine, bpy, to afford complexes [Mo(NNPh2)2Br2(o-phen)], I, and [Mo(NNPh2)2Br2(bpy)], II. These complexes have been characterized by IR, UV-vis and 1H NMR spectroscopies, and elemental analysis. The structure of complex I was solved by single crystal X-ray diffraction. The metal center has a distorted octahedral environment in which the diphenylhydrazido(2-) ligands occupy mutually cis positions but trans to the nitrogen atoms of the o-phen ligand. The bromo ligands occupy mutually trans positions. | |
| Lenguage | dc.language.iso | en | |
| Type of license | dc.rights | Attribution-NonCommercial-NoDerivs 3.0 Chile | |
| Link to License | dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/cl/ | |
| Source | dc.source | Boletin de la Sociedad Chilena de Quimica | |
| Keywords | dc.subject | 2,2′-bipyridine | |
| Keywords | dc.subject | Hydrazido(1-) | |
| Keywords | dc.subject | Hydrazido(2-) | |
| Keywords | dc.subject | Molybdenum complex | |
| Keywords | dc.subject | O-phenanthroline | |
| Keywords | dc.subject | X-ray structure | |
| Título | dc.title | Reactivity of [Mo(NHNPH2)(NNPH2)Br2(acac)] toward di-imines. X-ray crystal structure of [Mo(NNPH2)2Br2(o-phen)] | |
| Document type | dc.type | Artículo de revista | |
| Cataloguer | uchile.catalogador | SCOPUS | |
| Indexation | uchile.index | Artículo de publicación SCOPUS | |
| uchile.cosecha | uchile.cosecha | SI |
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Except where otherwise noted, this item's license is described as Attribution-NonCommercial-NoDerivs 3.0 Chile