Author | dc.contributor.author | Toral Ponce, María Inés | |
Author | dc.contributor.author | Richter Duk, Pablo | |
Admission date | dc.date.accessioned | 2018-12-20T15:20:39Z | |
Available date | dc.date.available | 2018-12-20T15:20:39Z | |
Publication date | dc.date.issued | 1995 | |
Cita de ítem | dc.identifier.citation | Analytical Letters, Volumen 28, Issue 6, 1995, Pages 1083-1094 | |
Identifier | dc.identifier.issn | 1532236X | |
Identifier | dc.identifier.issn | 00032719 | |
Identifier | dc.identifier.other | 10.1080/00032719508002680 | |
Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/158851 | |
Abstract | dc.description.abstract | A simple, sensitive and selective first derivative spectrophotometric method has been developed for the determination of copper and iron in mixtures. The method is based on the recovery of the analytes, by liquid-liquid extraction, Integrated reaction with 5-pheny1-3-(4-pheny1-2-pyridiny1)- l,2,4-triazine (PPT) and perchlorate in dichioroethane and on the subsequent direct derivative spectrophotometric measurement using the zero-crossing approach for determination of both analytes. Copper and Iron were thus determined in the ranges 50 - 2500 ng/ml and 2–120 ng/ml, respecttvely, in the presence of one another. The detection limits achieved (3σ) were found to be 17 ng/ml of copper and 0.7 ng/ml of iron. The relative standard deviations were in all instances less than 3.1%. The proposed method was applied to the determination of both analytes in well water and the results were consistent with those provided by the AAS standard method. | |
Lenguage | dc.language.iso | en | |
Source | dc.source | Analytical Letters | |
Keywords | dc.subject | Copper | |
Keywords | dc.subject | Derivative spectrophotometry | |
Keywords | dc.subject | Iron | |
Keywords | dc.subject | Simultaneous determination | |
Keywords | dc.subject | Zero-crossing | |
Título | dc.title | Simultaneous determination of copper and iron by solvent extraction and first derivative spectrophotometry | |
Document type | dc.type | Artículo de revista | |
dcterms.accessRights | dcterms.accessRights | Acceso a solo metadatos | |
Cataloguer | uchile.catalogador | rvh | |
Indexation | uchile.index | Artículo de publicación SCOPUS | |
uchile.cosecha | uchile.cosecha | SI | |