The crystal structure of the hydrogen bonded molecular adduct thiobisphthalimide diphenylamine
Author
dc.contributor.author
Manriquez, V.
Author
dc.contributor.author
Diaz, C.
Author
dc.contributor.author
Copaja, S.
Author
dc.contributor.author
Gonzalez, G.
Admission date
dc.date.accessioned
2018-12-20T15:20:45Z
Available date
dc.date.available
2018-12-20T15:20:45Z
Publication date
dc.date.issued
1991
Cita de ítem
dc.identifier.citation
Phosphorus, Sulfur, and Silicon and the Related Elements, Volumen 63, Issue 3-4, 1991, Pages 377-383
Identifier
dc.identifier.issn
15635325
Identifier
dc.identifier.issn
10426507
Identifier
dc.identifier.other
10.1080/10426509108036843
Identifier
dc.identifier.uri
https://repositorio.uchile.cl/handle/2250/158899
Abstract
dc.description.abstract
The structure of the complex (PHL)2S. HN(C6H5)2 has been determined by single-crystal X-ray diffraction methods. The compound crystallizes in the triclinic system, space group P 1, with unit cell dimensions a = 896. 1, b = 1730. 8, c = 846. 7 pm; α = 88. 66°, β = 115.66°, λ = 93. 98° and Z = 2. In the adduct the thiobisphthalimide molecule is bonded to the diphenylamine through a C=Oż HN hydrogen bonding. UV-visible data reveal some charge transfer between the donor HN(C6H5)2 and the acceptor (PHL)2S.