Interactions of neutral molecules with ionic micelles
Author
dc.contributor.author
Sepúlveda, Luis
Author
dc.contributor.author
Lissi Gervaso, Eduardo A.
Author
dc.contributor.author
Quina, Frank
Admission date
dc.date.accessioned
2019-01-29T12:39:47Z
Available date
dc.date.available
2019-01-29T12:39:47Z
Publication date
dc.date.issued
1986
Cita de ítem
dc.identifier.citation
Advances in Colloid and Interface Science, Volumen 25, Issue C, 1986, Pages 1-57
Identifier
dc.identifier.issn
00018686
Identifier
dc.identifier.other
10.1016/0001-8686(86)80001-X
Identifier
dc.identifier.uri
https://repositorio.uchile.cl/handle/2250/159641
Abstract
dc.description.abstract
The interactions of neutral molecules with ionic micelles are analyzed.
The cell and mass action models are presented in order to provide a semiquantitative description of the solubilization process. Both approaches are discussed from a thermodynamic and kinetic point of view and the different
definitions of solute incorporation constants are also discussed and compared.
An extensive compilation of standard free energies of transfer from water to
micelles is provided and the basis of the employed methods to obtain them is
presented. Several aspects of the solubilization process such as its dynamics,
the effect of additives, the probe microenvironment and its dependence with
the solute mean occupation number are reviewed and critically discussed. The
effect of solute incorporation upon the micelle shape and size is also briefly
reviewed.