Browsing by Author "dcfcfbbc-26a5-4ee6-b604-d1b00008c58d"
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García Ruano, José L.; Barros, David; Maestro, M. Carmen; Araya Maturana, Ramiro; Fischer, Jean (1996)Aldol reactions lithium alkyl acetates (LiCRR″CO2R′) with (RS)-2-(p-tolylsulfinyl)cyclohexanone (1) (as an epimeric mixture at C-2) take place with very efficient control of the configuration at the tertiary hydroxylic ...
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Almodovar, Iriux; Cardona, Wilson; Delgado Castro, Tomás; Zapata Torres, Gerald; Caroli Rezende, Marcos; Araya Maturana, Ramiro; Maestro, M. Carmen; García Ruano, José L. (2013)Diels-Alder cycloaddition of 8,8-dimethylnaphthalene-1,4,5(8H)-trione with diastereomeric hydroxysulfinyldienes proceeded with high yields and good π-facial and regioselectivities. The hydroxysulfoxide moiety controls the ...
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Maestro, M. Carmen; Fernández-Salas, José Antonio; García Ruano, José L.; Ramírez-Rodríguez, Oney O.; Araya Maturana, Ramiro (2012)The ability of a homochiral sulfinyl group at the dienophile to act as a remote stereocontrol inductor in the Diels-Alder reaction with cyclopentadiene has been evaluated. High pressure conditions were required for the ...