Browsing by Subject "Complexes"
Now showing items 1-13 of 13
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(2003)It has been shown that innocent ligands always contribute with a similar electron density to a metal centre in a complex regardless of which other innocent ligands are bonded to the same centre, while non-innocent ligands ...
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(Sociedad Chilena de Química, 2017)The mononuclear cobalt (III) complex derived from 1,10-phenanthroline with lactose [Co(phen)(2)lactose]Cl-2 center dot 3H(2)O (1) has been prepared and its properties have been compared with the sucrose complex ...
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(Elsevier, 2017)As a novel strategy to overcome some of the therapeutic disadvantages of 6-thioguanine (TG) and 6-mercaptopurine (MP), we propose the inclusion of these drugs in beta cyclodextrin (beta CD) to form the complexes beta CD-TG ...
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(American Chemical Society, 2020)To study how second-sphere interactions affect single-molecule magnet (SMM) properties of mononuclear lanthanide systems, two dysprosium(III) complexes [Dy(N-NCS)(3)(H2O)(5)]center dot 0.45(KSCN)(18-crown-6) (1) and ...
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(2004)A series of dinuclear iron (III) complexes with carboxylate bridges, of the type [Fe2L2(H20)4](NO 3)2(H2O)m (m=1-3), where L=Schiff base derived from L-α-amino acids and salicylaldehyde have been prepared and characterised ...
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(Royal Society of Chemistry, 2020)The uses of the sulfur-gold bond in the design of new molecular clusters have gained increasing attention in recent years. Their size and shape are diverse providing a wide variety of optical and electronic properties. ...
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(American Chemical Society, 2015)The first borate-vacant deca-vanadoborate of formula (NH3CH2CH2CH2NH3)(5) [ (NH3CH2CH2CH2NH3)V10B24O66H8]center dot 13.23H(2)O with an occluded 1;3-propanediammonium cation; using molten methylboronic acid flux reaction ...
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(Hindawi, 2020)Four indole-3-carbaldehyde semicarbazone derivatives, 2-((5-bromo-1H-indol-3-yl)methylene)hydrazinecarboxamide (1), 2-((5-chloro-1H-indol-3-yl)methylene)hydrazinecarboxamide (2), 2-((5-methoxy-1H-indol-3-yl)methylene)hyd ...
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(Royal Soc Chemestry, 2018)Two closed and one open structural forms of the interpenetrated [Cu-2(Tae)(Bpa)(2)](NO3)(2) center dot nH(2)O (H(2)Tae = 1,1,2,2-tetraacetylethane, Bpa = 1,2-bis(4-pyridyl) ethane) cationic coordination polymer have been ...
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Physical properties of new ordered bimetallic phases M0.25Cd0.75PS3 (M = Zn-II, Ni-II, Co-II, Mn-II) (Royal Society of Chemistry, 2020)Four bimetallic phases of the thiophosphate family have been synthesized by the cationic exchange reaction using a freshly prepared K0.5Cd0.75PS3 precursor phase and methanolic solutions of nitrates of the divalent cations ...
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(Springer, 2020)A mixture of a nanostructured Rh/RhO(2)phase was easily obtained by thermally treating the macromolecular Chitosan center dot(RhCl3)(x)precursor, while the Rh/Rh(2)O(3)phase was obtained by pyrolyzing PSP-4-PVP center ...
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(Amer Chemical Soc, 2020)We present experimental and theoretical studies of single-molecule conductance through nonplanar fullerocurcuminoid molecular dyads in ambient conditions using the mechanically controllable break junction technique. We ...
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(Kluwer Academic/Plenum Publishers, 1999)The reaction of copper(I) bromide, CuBr, with the tetraalkylthiurammonosulfides R4tms (R = iPr, nPr) affords the copper(I) complexes iPr4tmsCuBr (I) (C14H28BrCuN2S2, orthorhombic, Pna21, Z = 4, a = 12.487(2), b = 12.699(2), ...