Browsing by Author "Wittke, Oscar"
Now showing items 1-2 of 2
-
Klahn, A. Hugo; Toro, Adriana; Oelckers, Beatriz; Buono-Core, Gonzalo E.; Manríquez Castro, Víctor; Wittke, Oscar (American Chemical Society, 2006-06-26)Photochemical reaction of (eta(5)-C5R5)Re(CO)3 (R = H, Me) with pentachlorobenzene (lambda = 350 nm, hexane solution) yields trans-(eta(5)-C5R5)Re(CO)(2)(2,3,4,5-C6HCl4) (trans-1, R = Me; 2, R = H) formed by insertion of ...
-
Leiva, Carmen; Klahn, A. Hugo; Godoy, Fernando; Toro, Adriana; Manríquez Castro, Víctor; Wittke, Oscar; Sutton, Derek (American Chemical Society, 1999-02)Reaction of Cp*Re(CO)(2)I-2 with methylcopper affords cis-Cp*Re(CO)(2)(Me)I, which converts to the trans isomer on prolonged reaction or in the presence of neutral alumina. The X-ray structure of the trans isomer has been ...