| Author | dc.contributor.author | Miño Galaz, Germán | |
| Author | dc.contributor.author | Contreras Ramos, Renato | es_CL |
| Admission date | dc.date.accessioned | 2010-07-21T20:15:33Z | |
| Available date | dc.date.available | 2010-07-21T20:15:33Z | |
| Publication date | dc.date.issued | 2010 | |
| Cita de ítem | dc.identifier.citation | Chemical Physics Letters 486 (2010) 119–122 | en_US |
| Identifier | dc.identifier.other | doi:10.1016/j.cplett.2010.01.002 | |
| Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/119081 | |
| Abstract | dc.description.abstract | Hydrogen bond shortening and strengthening induced by confinement within fullerenes for a series of
hydrogen bonded bihalides were studied. Significant increase in the electron localizability at the hydrogen
bond region occurs as the confinement takes place. This result suggests that in confined systems
there are additional effects that are beyond the ‘electrostatic only’ explanation offered for the existence
of short and strong hydrogen bonds. We propose that these additional effects are factors on which the
enhanced bonding strength energetic stabilization and basicity also depend. | en_US |
| Patrocinador | dc.description.sponsorship | Fondecyt Grant’s 1070715. G. Miño thanks to Universidad Andres
Bello and to Comisión Nacional de Investigación Científica y
Tecnológica (CONICYT) for doctoral fellowships awarded to him. | en_US |
| Lenguage | dc.language.iso | en | en_US |
| Publisher | dc.publisher | Elsevier | en_US |
| Título | dc.title | Non-electrostatic components of short and strong hydrogen bonds induced by compression inside fullerenes | en_US |
| Document type | dc.type | Artículo de revista | |
