Author | dc.contributor.author | Osorio Olivares, Mauricio | |
Author | dc.contributor.author | Caroli Rezende, Marcos | es_CL |
Author | dc.contributor.author | Sepúlveda Boza, Silvia | es_CL |
Author | dc.contributor.author | Cassels Niven, Bruce | es_CL |
Author | dc.contributor.author | Baggio, Ricardo | es_CL |
Author | dc.contributor.author | Muñoz Acevedo, Juan Carlos | es_CL |
Admission date | dc.date.accessioned | 2012-06-06T19:17:12Z | |
Available date | dc.date.available | 2012-06-06T19:17:12Z | |
Publication date | dc.date.issued | 2003-03-12 | |
Cita de ítem | dc.identifier.citation | Tetrahedron: Asymmetry Vol. 14, p. 1473–1477, 2003. | es_CL |
Identifier | dc.identifier.issn | 0957-4166 | |
Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/119463 | |
Abstract | dc.description.abstract | Abstract—A simple method for the preparation of homochiral ring-substituted 1-aryl-2-aminopropanones 2 (‘cathinones’) is
described, involving initial Friedel–Crafts acylation of aromatics with (S)- or (R)-N-trifluoroacetylalanyl chloride, followed by
acid hydrolysis of the intermediate trifluoroacetamido intermediates 1, for which X-ray diffraction analysis confirmed the
structures. | es_CL |
Patrocinador | dc.description.sponsorship | This work was supported by FONDECYT Grant Nos.
1000776 and 1020802, FONDAP Grant No. 11980002
Fundacio´n Andes (C-13575) and USACH-DICYT.
J.C.M.-A. is a grateful recipient of a DAAD scholarship,
and M.O.-O. of CONICYT and MECESUP
(USA 9903) scholarships. | es_CL |
Lenguage | dc.language.iso | en | es_CL |
Publisher | dc.publisher | Elsevier Science Ltd. | es_CL |
Título | dc.title | A two-step method for the preparation of homochiral cathinones | es_CL |
Document type | dc.type | Artículo de revista | |