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Authordc.contributor.authorJullian Matthaei, Carolina 
Authordc.contributor.authorOrosteguis, Teresita es_CL
Authordc.contributor.authorPérez Cruz, Fernanda es_CL
Authordc.contributor.authorSánchez, Paulina es_CL
Authordc.contributor.authorMendizábal Emaldía, Fernando es_CL
Authordc.contributor.authorOlea Azar, Claudioes_CL
Admission datedc.date.accessioned2008-11-10T14:49:44Z
Available datedc.date.available2008-11-10T14:49:44Z
Publication datedc.date.issued2008-11-01
Cita de ítemdc.identifier.citationSPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 71(1):269-275en
Identifierdc.identifier.issn1386-1425
Identifierdc.identifier.urihttps://repositorio.uchile.cl/handle/2250/120554
Abstractdc.description.abstractProperties of inclusion complexes between morin (M) and beta-cyclodextrin (beta CD), 2-hydroxypropyl-beta-cyclodextrin (HP beta CD) and Heptakis (2,6-O-di methyl) beta-cycloclextrin (DM beta CD) such as aqueous solubility and the association constants of this complex have been determined. The water solubility of morin was increased by inclusion with cyclodextrins. The phase-solubility diagrams drawn from UV spectral measurements are of the A(L)-type. Also ORAC(FL). studies were done. An increase in the antioxidant reactivity is observed when morin form inclusion complex with the three cyclodextrin studied. Finally, thermodynamics studies of cyclodextrin complexes indicated that for DM beta CD the inclusion is primarily enthalpy-driven process meanwhile beta CD and HP beta CD are entropy-driven processes. This is corroborated by the different inclusion geometries obtained by 2D-NMR.en
Lenguagedc.language.isoenen
Publisherdc.publisherPERGAMON-ELSEVIER SCIENCE LTDen
Keywordsdc.subjectRADICAL ABSORBENCY CAPACITYen
Títulodc.titleComplexation of morin with three kinds of cyclodextrin - A thermodynamic and reactivity studyen
Document typedc.typeArtículo de revista


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