Nonacarbonyl[mu(3)-(1,2-diphenylethyl)-phenylphosphinito]triosmium(2 Os-Os)

Author	dc.contributor.author	Capparelli, Mario V.
Author	dc.contributor.author	DeSanctis, Y.	es_CL
Author	dc.contributor.author	Arce, A. J.	es_CL
Author	dc.contributor.author	Spodine Spiridonova, Evgenia	es_CL
Admission date	dc.date.accessioned	2010-11-16T15:55:58Z
Available date	dc.date.available	2010-11-16T15:55:58Z
Publication date	dc.date.issued	1997-03-15
Cita de ítem	dc.identifier.citation	ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS 53: 302-305 Part: 3	en_US
Identifier	dc.identifier.issn	0108-2701
Identifier	dc.identifier.uri	https://repositorio.uchile.cl/handle/2250/121119
Abstract	dc.description.abstract	The reaction of 1,2,3-triphenylphosphirene with [H2Os3-(CO)(10)] leads to the title compound, [Os-3(CO)(9){(C6H5)(3)-C2PO}], which displays an open Os-3(CO)(9) cluster [Os-Os 2.703(1) and 2.867(2) Angstrom, and Os-Os-Os 124.24(4)degrees]. This moiety is mu(3),eta(3)-bonded to a phosphirene ligand with a cleaved P-C bond, PhC-C(Ph)-P. An O atom was incorporated into the molecule resulting in an unusual five-membered metallacycle, Os-C-C-P-O, with distances Os-C 2.10(1), C-C 1.46(2), C-P 1.76(1), P-O 1.628(9) and O-Os 2.136(9) Angstrom. This ring makes a dihedral angle of 57.3(2)degrees with the plane of the metal atoms.	en_US
Lenguage	dc.language.iso	en	en_US
Publisher	dc.publisher	MUNKSGAARD INT PUBL LTD	en_US
Keywords	dc.subject	PHOSPHORUS-CARBON BOND	en_US
Título	dc.title	Nonacarbonyl[mu(3)-(1,2-diphenylethyl)-phenylphosphinito]triosmium(2 Os-Os)	en_US
Document type	dc.type	Artículo de revista