Origin of chirality in charge transfer bands of Cu(II) acidates

Author	dc.contributor.author	Bunel Torrealba, Sergio	es_CL
Author	dc.contributor.author	Ibarra, Carmen	es_CL
Author	dc.contributor.author	Rodríguez, M.	es_CL
Author	dc.contributor.author	Urbina, A.
Author	dc.contributor.author	Bunton, Clifford A.
Admission date	dc.date.accessioned	2011-06-10T19:49:32Z
Available date	dc.date.available	2011-06-10T19:49:32Z
Publication date	dc.date.issued	1981
Cita de ítem	dc.identifier.citation	Journal of Inorganic and Nuclear Chemistry 43: 971-975	es_CL
Identifier	dc.identifier.issn	0022-1902
Identifier	dc.identifier.uri	https://repositorio.uchile.cl/handle/2250/121270
Abstract	dc.description.abstract	Complexes of Cu(II) with L-aminoacids have positive charge transfer bands in their CD spectra at ca.230 nm and negative at ca. 270 nm. Examination of complexes with L-1,2-diamino propane shows that the positive band is due to charge transfer from nitrogen and the negative from oxygen to copper. This sign difference is consistent with a theoretical model. The effects of added nonchiral ligands on the CD spectra in the charge transfer region are analyzed.	es_CL
Lenguage	dc.language.iso	en	es_CL
Publisher	dc.publisher	Pergamon Press	es_CL
Keywords	dc.subject	Cu(II)	es_CL
Título	dc.title	Origin of chirality in charge transfer bands of Cu(II) acidates	es_CL
Document type	dc.type	Artículo de revista