Crystal structure and electronic and magnetic properties of hexacyanoosmate(III)
Author | dc.contributor.author | Albores, Pablo | |
Author | dc.contributor.author | Slep, Leonardo D. | es_CL |
Author | dc.contributor.author | Baraldo, Luis M. | es_CL |
Author | dc.contributor.author | Baggio, Ricardo | es_CL |
Author | dc.contributor.author | Garland, María Teresa | es_CL |
Author | dc.contributor.author | Rentschler, Eva | es_CL |
Admission date | dc.date.accessioned | 2008-12-04T14:55:24Z | |
Available date | dc.date.available | 2008-12-04T14:55:24Z | |
Publication date | dc.date.issued | 2006-03-20 | |
Cita de ítem | dc.identifier.citation | INORGANIC CHEMISTRY Volume: 45 Issue: 6 Pages: 2361-2363 Published: MAR 20 2006 | en |
Identifier | dc.identifier.issn | 0020-1669 | |
Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/124737 | |
Abstract | dc.description.abstract | The [Os-III(CN)(6)](3-) anion is prepared by chemical oxidation in aqueous solution and isolated as yellow prisms of [Ph4P](3)[OSIII(CN)(6)]center dot 6H(2)O (1). This species crystallizes in the triclinic space group Of with cell parameters a = 13.7609(11) angstrom, b = 16.2275(13) angstrom, c = 17.0895(14) angstrom, alpha = 91.4040(10)degrees, beta = 109.3600(10)degrees, gamma = 102.3970(10)degrees, V = 3497.4(5) angstrom(3), and Z = 2. The slightly distorted octahedral moiety displays Os-C and C-N bond lengths that average 2.058 and 1.146 angstrom, respectively, Spin-orbit-coupling splitting of the ground-state term dominates the NIR region of the electronic spectrum and the magnetic behavior of 1. The experimental information points to higher spin delocalization over the coordinated cyanides than in [Fe-III(CN)(6)](3-). | en |
Lenguage | dc.language.iso | en | en |
Publisher | dc.publisher | AMER CHEMICAL SOC | en |
Keywords | dc.subject | HEXACYANOMETALATE COMPLEXES | en |
Título | dc.title | Crystal structure and electronic and magnetic properties of hexacyanoosmate(III) | en |
Document type | dc.type | Artículo de revista |
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