An unusual two-dimensional hydrogen-bonding network in bis(2,9-dimethyl-1,10-phenanthrolin-1-ium) peroxodisulfate dihydrates
Author | dc.contributor.author | Harvey, Miguel Angel | |
Author | dc.contributor.author | Baggio, Sergio | es_CL |
Author | dc.contributor.author | Garland, María Teresa | es_CL |
Author | dc.contributor.author | Baggio, Ricardo | es_CL |
Admission date | dc.date.accessioned | 2010-01-26T13:50:35Z | |
Available date | dc.date.available | 2010-01-26T13:50:35Z | |
Publication date | dc.date.issued | 2008-09 | |
Cita de ítem | dc.identifier.citation | ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS Volume: 64 Pages: O489-O492 Part: Part 9 Published: SEP 2008 | en_US |
Identifier | dc.identifier.issn | 0108-2701 | |
Identifier | dc.identifier.other | 10.1107/S0108270108024360 | |
Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/125233 | |
Abstract | dc.description.abstract | The title compound, 2C(14)H(13)N(2)(+)center dot S2O82-center dot 2H(2)O, is a protonated amine salt which is formed from two rather uncommon ionic species, namely a peroxodisulfate (pds(2-)) anion, which lies across a crystallographic inversion centre, and a 2,9-dimethyl1,10-phenanthrolin-1-ium (Hdmph(+)) cation lying in a general position. Each pds(2-) anion binds to two water molecules through strong water-peroxo O-H center dot center dot center dot O interactions, giving rise to an unprecedented planar network of hydrogen-bonded macrocycles which run parallel to (100). The atoms of the large R-8(8)(30) rings are provided by four water molecules bridging in fully extended form (center dot center dot center dot H-O-H center dot center dot center dot) and four pds(2-) anions alternately acting as long (center dot center dot center dot O-S-O-O-S-O center dot center dot center dot) and short (center dot center dot center dot O-S-O center dot center dot center dot) bridges. The Hdmph(+) cations, in turn, bind to these units through hydrogen bonds involving their protonated N atoms. In addition, the crystal structure also contains pi-pi and aromatic-peroxo C-H center dot center dot center dot O interactions. | en_US |
Lenguage | dc.language.iso | en | en_US |
Publisher | dc.publisher | BLACKWELL PUBLISHING | en_US |
Keywords | dc.subject | CRYSTAL-STRUCTURE | en_US |
Título | dc.title | An unusual two-dimensional hydrogen-bonding network in bis(2,9-dimethyl-1,10-phenanthrolin-1-ium) peroxodisulfate dihydrates | en_US |
Document type | dc.type | Artículo de revista |
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