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A novel copper(II)-lanthanum(III) metal organic framework as a selective catalyst for the aerobic oxidation of benzylic hydrocarbons and cycloalkenes

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Date
2016
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Cancino, P.
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A novel copper(II)-lanthanum(III) metal organic framework as a selective catalyst for the aerobic oxidation of benzylic hydrocarbons and cycloalkenes
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Author
  • Cancino, P.;
  • Vega, Andrés;
  • Santiago Portillo, Andrea;
  • Navalon, Sergio;
  • Alvaro, Mercedes;
  • Aguirre Álvarez, Pedro;
  • Spodine Spiridonova, Evgenia;
  • García, Hermenegildo;
Abstract/Review
The synthesis and structure of a novel heteronuclear Cu-II and La-III metal organic framework (MOF) having pyridinedicarboxylic acid (CuLa-MOF) is reported. The obtained MOF with the formula {[Cu0.5La2(HPDC)(PDC)(2)(SO4)(H2O)(2)]H2O}(n) (PDC: 3,5-pyridinedicarboxylate) has a 3D non-porous lattice with a single type of octahedrally coordinated Cu-II and two distinct nonacoordinated LaIII ions, with sulphate being a linker between the Cu-II and La-III centers. CuLa-MOF exhibits catalytic activity to promote the aerobic autooxidation of benzylic hydrocarbons and the aerobic oxidation of cycloalkenes. Compared with a homogenous catalyst, Cu(OAc)(2), CuLa-MOF, as a heterogeneous catalyst, exhibits similar activity, but the solid is recyclable with some minor decrease in activity from the first to the second catalytic cycle; after which, a steady activity is observed, as determined by the coincidence of temporal evolution of the reaction upon reuse
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URI: http://repositorio.uchile.cl/handle/2250/141328
DOI: 10.1039/c5cy01448d
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Catalysis Science & Technology Volumen 6 Número: 11 Páginas: 3727-3736
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