Coordinating properties of some solvents in Cr(CO)5L complexes
item_0012622058.pdf (1.748Kb)Abstract
The influence of the donor-acceptor properties of several solvents on the Cr(CO)5 group in the solid [Cr(CO)5·solvent] complexes has been examined by spectroscopic methods. Relationships were found between the acceptor number of solvent with the π acceptor ability (Graham π parameter) and with the λmax for the ligand field 1A1 → 1E transition, in the carbonyl chromium complexes. These relations are discussed in terms of the dative metal-ligand π bonding. From these results, it is possible to demonstrate the π contribution in the acceptor number. © 1988 Pergamon Press plc.
Indexation
Artículo de publicación SCOPUS
Identifier
URI: https://repositorio.uchile.cl/handle/2250/156644
DOI: 10.1016/S0277-5387(88)80036-6
ISSN: 02775387
Quote Item
Polyhedron, Volumen 7, Issue 9, 2018, Pages 673-677
Collections
Except where otherwise noted, this item's license is described as Attribution-NonCommercial-NoDerivs 3.0 Chile