Show simple item record

Electrochemical reduction of nitrotetralones

Authordc.contributor.authorSquella Serrano, Juan 
Authordc.contributor.authorHuerta, M 
Authordc.contributor.authorBollo Dragnic, Soledad 
Authordc.contributor.authorPessoa, H 
Authordc.contributor.authorNúñez Vergara, Luis 
Admission datedc.date.accessioned2018-12-20T15:09:17Z
Available datedc.date.available2018-12-20T15:09:17Z
Publication datedc.date.issued1997
Cita de ítemdc.identifier.citationJournal of Electroanalytical Chemistry, Volumen 420, Issue 1-2, 1997, Pages 63-69
Identifierdc.identifier.issn15726657
Identifierdc.identifier.other10.1016/S0022-0728(96)04819-X
Identifierdc.identifier.urihttp://repositorio.uchile.cl/handle/2250/158007
Abstractdc.description.abstractThe electrochemical reduction of three nitrotetralone derivatives by tast and differential pulse polarography and cyclic voltammetry in a wide pH range was studied. In aqueous media, the reduction of mono- and dinitrotetralone follows the general pattern of reduction of aromatic nitro compounds: the nitro group is reduced in a four-electron step to a hydroxylamine group. However, in mixed media this reduction differs from that of other nitrobenzenes, due to the fact that the formation of the nitroradical anion was not observed. The reduction of the acetoxy derivative was studied only at alkaline pH, because it suffered acid hydrolysis. The ionization pK of the protonatable groups were polarographically obtained.
Lenguagedc.language.isoen
Publisherdc.publisherElsevier
Sourcedc.sourceJournal of Electroanalytical Chemistry
Keywordsdc.subjectNitroaromatic reduction
Keywordsdc.subjectNitrotetralone
Keywordsdc.subjectPolarographic reduction
Títulodc.titleElectrochemical reduction of nitrotetralones
Document typedc.typeArtículo de revista
Catalogueruchile.catalogadorrvh
Indexationuchile.indexArtículo de publicación SCOPUS
Access notedct.AccessRightsSin acceso a texto completo
uchile.cosechauchile.cosechaSI


Files in this item

Icon

This item appears in the following Collection(s)

Show simple item record