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Author dc.contributor.author Moya, S. A.
Author dc.contributor.author Vidal, M.
Author dc.contributor.author Abarca, G.
Author dc.contributor.author Martinez, C.
Author dc.contributor.author Guerchais, V.
Author dc.contributor.author Le Bozec, H.
Author dc.contributor.author Garland, María Teresa
Author dc.contributor.author Rodriguez, S.
Author dc.contributor.author Aguirre, P.
Admission date dc.date.accessioned 2018-12-20T15:10:29Z
Available date dc.date.available 2018-12-20T15:10:29Z
Publication date dc.date.issued 2010
Cita de ítem dc.identifier.citation Inorganic Chemistry Communications, Volumen 13, Issue 12, 2018, Pages 1519-1521
Identifier dc.identifier.issn 13877003
Identifier dc.identifier.other 10.1016/j.inoche.2010.09.001
Identifier dc.identifier.uri https://repositorio.uchile.cl/handle/2250/158197
Abstract dc.description.abstract The synthesis and characterization of new ruthenium(II) carbonyl complexes containing polypyridine and triphenylphosphine ligands is reported. Crystallographic information obtained for the trans-PPh3-[Ru(biq) (PPh3)2(CO)]Cl2 complex (biq = 2,2'-biquinoline) reveals five-coordination on the metal. The complexes were studied as catalysts in hydrogen transfer reactions in basic solution. Turnover frequencies in the 2250-817 h-1 range were determined in 1 hour of reaction with a substrate/catalysts ratio of 830. © 2010 Elsevier B.V. All rights reserved.
Lenguage dc.language.iso en
Type of license dc.rights Attribution-NonCommercial-NoDerivs 3.0 Chile
Link to License dc.rights.uri http://creativecommons.org/licenses/by-nc-nd/3.0/cl/
Source dc.source Inorganic Chemistry Communications
Keywords dc.subject Polypyridine ligands
Keywords dc.subject Ruthenium carbonyl
Keywords dc.subject Ruthenium complex
Keywords dc.subject Transfer hydrogenation
Título dc.title Synthesis, structure and catalytic activities for hydrogen transfer reaction of the carbonyl ruthenium(II) complex containing polypyridine and phosphine ligands
Document type dc.type Artículo de revista
Cataloguer uchile.catalogador SCOPUS
Indexation uchile.index Artículo de publicación SCOPUS
uchile.cosecha uchile.cosecha SI
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