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1D magnetic interactions in Cu

Authordc.contributor.authorVenegas Yazigi, Diego 
Authordc.contributor.authorSpodine Spiridonova, Evgenia 
Authordc.contributor.authorSaldias, Marianela 
Authordc.contributor.authorVega, Andrés 
Authordc.contributor.authorParedes García, Verónica 
Authordc.contributor.authorCalvo, Rafael 
Authordc.contributor.authorSantana, Ricardo Costa De 
Admission datedc.date.accessioned2018-12-20T15:11:01Z
Available datedc.date.available2018-12-20T15:11:01Z
Publication datedc.date.issued2015
Cita de ítemdc.identifier.citationInorganic Chemistry, Volumen 54, Issue 8, 2018, Pages 3805-3814
Identifierdc.identifier.issn1520510X
Identifierdc.identifier.issn00201669
Identifierdc.identifier.other10.1021/ic503045d
Identifierdc.identifier.urihttp://repositorio.uchile.cl/handle/2250/158357
Abstractdc.description.abstract© 2015 American Chemical Society. We report the crystal face indexing and molecular spatial orientation, magnetic properties, electron paramagnetic resonance (EPR) spectra, and density functional theory (DFT) calculations of two previously reported oxovanadium phosphates functionalized with Cu<sup>II</sup> complexes, namely, [Cu(bipy)(VO<inf>2</inf>)(PO<inf>4</inf>)]<inf>n</inf> (1) and [{Cu(phen)}<inf>2</inf>(VO<inf>2</inf>(H<inf>2</inf>O)<inf>2</inf>)(H<inf>2</inf>PO4)<inf>2</inf> (PO<inf>4</inf>)]<inf>n</inf> (2), where bipy = 2,2′-bipyridine and phen = 1,10-phenanthroline, obtained by a new synthetic route allowing the growth of single crystals appropriate for the EPR measurements. Compounds 1 and 2 crystallize in the triclinic group P1¯and in the orthorhombic Pccn group, respectively, containing dinuclear copper units connected by two -O-P-O- bridges in 1 and by a single -O-P-O- bridge in 2, further connected through -O-P-O-V-O- bridges. We emphasize in our work the structural asp
Lenguagedc.language.isoen
Publisherdc.publisherAmerican Chemical Society
Type of licensedc.rightsAttribution-NonCommercial-NoDerivs 3.0 Chile
Link to Licensedc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/cl/
Sourcedc.sourceInorganic Chemistry
Keywordsdc.subjectPhysical and Theoretical Chemistry
Keywordsdc.subjectInorganic Chemistry
Títulodc.title1D magnetic interactions in Cu
Document typedc.typeArtículo de revista
Catalogueruchile.catalogadorSCOPUS
Indexationuchile.indexArtículo de publicación SCOPUS
uchile.cosechauchile.cosechaSI


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Except where otherwise noted, this item's license is described as Attribution-NonCommercial-NoDerivs 3.0 Chile