Browsing by Author "201-0010791"
Now showing items 1-20 of 26
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Werner, R.; Weyrauch, T.; Navarrete Encina, Patricio; Haase, W.; Soto Bustamante, Eduardo (ELSEVIER SCIENCE BV, 2000-05-12)To clarify the mechanism involved in the appearance of antiferroelectric properties in mixtures of polymers containing achiral mesogenic side chains and their monomers, X-ray investigation was carried out in pyroelectrically ...
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Electrochemical and EPR characterization of 1,4-dihydropyridines. Reactivity towards alkyl radicals Núñez Vergara, Luis; López Alarcón, Camilo; Navarrete Encina, Patricio; Atria Salas, Ana María; Camargo Grandón, Rodrigo; Squella Serrano, Juan (TAYLOR & FRANCIS LTD, 2003)This work reports the electrochemical oxidation of a series of three synthesized 4-substituted-1,4-dihydropyridine derivatives in different electrolytic media. Also, an EPR characterization of intermediates and the reactivity ...
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Núñez Vergara, Luis; Santander Gutiérrez, Ingrid Paola; Navarrete Encina, Patricio; Valenzuela Pedevila, Jorge; Sturm Schaub, Juan; Squella Serrano, Juan (ELECTROCHEMICAL SOC, 2006)The present paper deals with the electrochemical and electron spin resonance (ESR) characterization of a number of nitroso phenyl 1,4-dihydropyridines in aprotic media on a hanging drop mercury electrode (HDME). The ...
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Núñez Vergara, Luis; Bontá, M.; Sturm, J. C.; Navarrete Encina, Patricio; Bollo Dragnic, Soledad; Squella Serrano, Juan (PERGAMON-ELSEVIER SCIENCE, 2001-08-31)This paper reports a comprehensive study by tast polarography, d.p.p., and cyclic voltammetry on the electrochemical reduction in different electrolytic media of ortho- and meta-nitrotoluene derivatives. Controlled potential ...
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Salazar González, Ricardo Andrés; Navarrete Encina, Patricio; Camargo Grandón, Rodrigo; Squella Serrano, Juan; Núñez Vergara, Luis (ELSEVIER SCIENCE SA, 2008-10-01)This work reports the electrochemical oxidation of two new synthetic C4-vanillin and -isovanillin-1,4-dihydropyridines in aprotic medium. Its reactivity with alkylperoxyl radicals ABAP-derived at pH 7.4 is also studied. ...
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Núñez Vergara, Luis; Santander, Paola; Navarrete Encina, Patricio; Squella Serrano, Juan (ELSEVIER, 2005-06-15)A comprehensive study of the electrochemical reduction in protic media of parent C-4 nitrophenyl 1,4-DHPs and their corresponding nitrosophenyl 1,4-DHPs was carried out. The reduction potentials of synthesized aromatic ...
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Núñez Vergara, Luis; Bontá, M.; Sturm Schaub, Juan; Navarrete Encina, Patricio; Bollo Dragnic, Soledad; Squella Serrano, Juan (ELSEVIER SCIENCE, 2001-06-15)A comprehensive study of the electrochemical reduction, in different electrolytic media, of two nitroso compounds, i.e. ortho- and meta-nitrosotoluene derivatives has been carried out. Furthermore, UV-vis and EPR spectroscopic ...
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Núñez Vergara, Luis; Sturm Schaub, Juan; Olea Azar, Claudio; Navarrete Encina, Patricio; Bollo Dragnic, Soledad; Squella Serrano, Juan (HARWOOD ACAD PUBL GMBH, 2000)This paper deals with the reactivity of the nitro radical anion electrochemically generated from nitrofurantoin with glutathione. Cyclic voltammetry (CV) and controlled potential electrolysis were used to generate the nitro ...
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Barrientos, C; Navarrete Encina, P.; Squella Serrano, Juan (Electrochemical Soc Inc, 2020)The present studies reveal superoxide radical anion reactivity against synthesized coumarins. Free radicals play an important role in many diseases and they have a protective function also. Therefore, we must keep a balance ...
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Núñez Vergara, Luis; Salazar González, Ricardo Andrés; Navarrete Encina, Patricio; Camargo Grandón, Rodrigo; Yáñez Soto, Claudia; Squella Serrano, Juan (ELECTROCHEMICAL SOC, 2007)A study of the electrolytic oxidation of three new C-4 nitrofuryl 1,4-dihydropyridines in nonaqueous aprotic medium is presented. Controlled-potential electrolysis (CPE) in dimethylformamide +0.1 M tetrabutyl-ammonium ...
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Pardo Jiménez, Viviana Gladys (Universidad de Chile, 2011)En la presente Memoria se hace un estudio sistemático sobre la síntesis de 9-metoxiy 9-nitro-cromenodihidropiridinas y cromenopiridinas substituídas, las cuales fueron posteriormente caracterizadas física y electroquímicamente. ...
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Navarrete Encina, Patricio; Weyrauch, T.; Soto Bustamante, Eduardo; Werner, R. (GORDON BREACH SCI PUBL LTD, 2000)In this paper we report on the synthesis and characterization of new mixtures of achiral liquid crystalline side-chain polymers with their monomers. The samples have a basic structure similar to materials prepared earlier ...
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Núñez Vergara, Luis; Squella Serrano, Juan; Olea Azar, Claudio; Bollo Dragnic, Soledad; Navarrete Encina, Patricio; Sturm Schaub, Juan (PERGAMON-ELSEVIER SCIENCE, 2000)This paper reports both the electrochemical characterization and the reactivity of the nitroso radical anion from nitrosobenzene with glutathione. The reduction of nitrosobenzene to the corresponding nitroso radical anion ...
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Salazar González, Ricardo Andrés; Navarrete Encina, Patricio; Camargo Grandón, Rodrigo; Squella Serrano, Juan; Núñez Vergara, Luis (ELECTROCHEMICAL SOC INC, 2008)Electrochemical oxidation of 4-(3-indolyl)- and 4-(5-indolyl)-1,4-dihydropyridines (DHPs) in aprotic and protic media is reported. Also, the reactivity of compounds toward alkylperoxyl radicals 2,2'-azobis-(2-amidinopropane) ...
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Núñez Vergara, Luis; Salazar González, Ricardo Andrés; Camargo Grandón, Rodrigo; Carbajo, J.; Conde, B.; Navarrete Encina, Patricio; Squella Serrano, Juan (PERGAMON-ELSEVIER SCIENCE, 2007-06-15)This work reports the electrochemical oxidation of three newly synthesized C4-hydroxyphenyl-substituted 1,4-dihydropyridine derivatives in dimethylsulfoxide. The reactivity of the compounds with ABAP-derived alkylperoxyl ...
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López Alarcón, Camilo; Navarrete Encina, Patricio; Camargo Grandón, Rodrigo; Squella Serrano, Juan; Núñez Vergara, Luis (AMER CHEMICAL SOC, 2003-02)A series of C4-substituted 1,4-dihydropyridines (DHP) with either secondary or tertiary nitrogen in the dihydropyridine ring were synthesized. All of these compounds together with some commercial DHP derivatives were tested ...
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Salazar González, Ricardo Andrés; Navarrete Encina, Patricio; Squella Serrano, Juan; Camargo Grandón, Rodrigo; Núñez Vergara, Luis (JOHN WILEY & SONS LTD, 2009-06)Reactivity of two new C4-indolyl substituted 1,4-dihydropyridines (1,4-DHPs) toward superoxide anion (O-2) in dimethylsulfoxide (DMSO) is reported. Reactivity was followed by electrochemical and spectroscopic techniques. ...
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Pérez Cruz, Karina Angélica (Universidad de Chile, 2010)La presente memoria da cuenta de la síntesis, caracterización física y electroquímica de cuatro nuevos compuestos: 1-etoxicarbonil-2,4-dimetil-5-oxo-5H-cromeno[3,4- c]dihidropiridina; 1-etoxicarbonil-2,4-dimetil-5-oxo- ...
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Vega Retter, Christián (Universidad de Chile, 2007)En la presente Memoria se describe la síntesis de cuatro nuevas cromeno[3,4- c]piridinas 7,8,9-hidroxi-substituidas y su caracterización electroquímica en medio no acuoso. Las cromeno-piridinas sintetizadas fueron: ...
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Pérez Cruz, Karina Angélica; Moncada-Basualto, Mauricio; Morales Valenzuela, Javier; Barriga González, Germán; Navarrete Encina, Patricio; Núñez Vergara, Luis; Squella Serrano, Juan; Olea Azar, Claudio (Elsevier, 2018-05)The antioxidant capacity of hydroxylated coumarins and hydroxybenzoic acids has been widely described. However, there is little information on the antioxidant activity when both systems are functionalized. In this work, ...