Facultad de Ciencias Químicas y Farmacéuticas: Recent submissions
Now showing items 1921-1940 of 5193
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(1975)Study of the visible absorption and circular dichroism spectra of mixed complexes formed by copper(II), an optically active amino acid anion and a phenanthroline or dipyridyl moiety, shows that although the absorption ...
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(1980)The photochemistry of alkanals in dilute solutions and in the presence of olefins and hydrogen donors was analysed and the results obtained are discussed taking as reference the photochemical behaviour of the alkanones. ...
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(1978)Kinetic studies of the [Co(phen)3] (ClO4)3 2H2O nitromethane pyridine reaction were made spectrophotometrically, by recording the appearance of a new absorption band at 474 nm. The reaction is first order with respect to ...
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(1979)Mössbauer spectroscopy as a function of temperature of Fe(II)(N,N′-dicyclohexyl-thiourea)6(ClO4)2(FeDCTU) shows the existence of two isomeric forms A and B which coexist in the temperature range 200 < T < 300 K. The relative ...
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(2006)Free radicals may be reaction intermediates in biological systems in more situations than are presently recognized. However, progress in detecting such species by Electron Spin Resonance (ESR) has been relatively slow. ESR ...
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(2008)Cu(2+) ions and and GSH molecules interact swiftly to form the complex Cu(I)–glutathione. We investigated the potential capacity of such complex to reduce molecular oxygen. The addition of SOD to a solution containing ...
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(1992)Two forms of ATP-diphosphohydrolase were identified in Solanum tuberosum tuber var. Ultimus. Their hydrolytic activity ratios (ATPase/ADPase) were over 10 for form A and 1 for form B. In the potato tuber homogenate the ...
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(2004)To evaluate the potential use of mesquite (Prosopis chilensis (Mol) Stuntz) seed gum, the behaviour of the gum was studied using two extraction methods (alkaline and acid), different pH values, two concentrations (0.2 and ...
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(1993)Four sodium polysoaps from poly[malcic anbydride-co-styrene] were synthesized and the surface properties of their aqueous solutions at the air-water interface were determined. The surface tension lowering was directly ...
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(2004)The oxidation of D-galacturonic acid by Cr-VI yields the aldaric acid and Cr-III as final products when a 30-times or higher excess of the uronic acid over Cr-VI is used. The redox reaction involves the formation of ...
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(2004)Gelation of fresh (unfrozen) raw surimi-type paste (RS paste) from horse mackerel (T. murphyi) was studied in the presence of κ-carrageenan (0.5, 1, 2% Cκ) and KCl (0.5-2%) as a substitute for NaCl. Gelation was traced by ...
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(Instituto de la Grasa, 2007)The announcement made by Swedish researches in April 2002 concerning the detection of acrylamide in many different foods, has generated a great deal of scientific publications coming from different parts of the world. The ...
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(2008)A series of five compounds containing the bicyclo-[3.3.0]octa-2,6-diene skeleton are described, namely tetra-methyl cis,cis-3,7-dihydroxy-bicyclo-[3.3. 0]octa-2,6-diene-2,4-exo,6,8-exo-tetracarboxyl-ate, C16H18O10, (I), ...
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(2008)Despite many advances achieved to date, heart failure (HF) remains a leading cause of morbidity and mortality. There is a widely-accepted consensus that HF and diabetes are strongly linked by at least 3 mechanisms: associated ...
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(2004)Biomineralization leads to the formation of inorganic crystals with unique, ordered, refined shapes that are regulated by specific macromolecules. This process has been a source of inspiration for exploring novel approaches ...
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(2002)We discuss a nonhomogeneous population of pulsatil integrate-and-fire neural oscillators, coupled through purely inhibitory synapses. For instantaneous communication, we provide a strategy to generate synaptic couplings ...
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(2006)HTLV-1-associated myelopathy/tropical spastic paraparesis (TSP/HAM) is a chronic CNS disease characterized by axomyelinic degeneration of the long axons of corticospinal tracts. Levels of NGF, NT-3, NT-4/5, BDNF, GDNF, ...
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(Society of Biology of Chile, 2007)The antioxidant effect of 5-Aminosalicylic acid (5-ASA) on copper-mediated LDL oxidation was followed either by the emitted chemiluminiscence (CL) or by UV-vis spectroscopy. 5-ASA addition extends the lag phase in a ...
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(2007)Three new dinuclear Zn(II) complexes [Zn(L)(μ1,1-N3)Zn(L)(N3)] · 1.5H2O (1), [Zn(L)(μ1,1-NCO)Zn(L)(NCO)] · 1.5H2O (2) and [Zn(L)(μ1,1-NCS)Zn(L)(NCS)(OH2)] (3) have been synthesized from a potentially tetradentate N2O2-donor ...
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(1980)We describe a procedure for the preparation of various metal thiourea complexes of the type [M(CO)5L] in which M Cr or W and L TU (thiourea), TMTU (tetramethylthiourea), DptTU (NN′-di-p-totyl thiourea); DtBTU = (NN′-di-t-butyl ...
