Reactivity of the carbon-carbon double bond towards nucleophilic additions. A DFT analysis

Author	dc.contributor.author	Domingo, Luis R.
Author	dc.contributor.author	Pérez López, Patricia	es_CL
Author	dc.contributor.author	Contreras Ramos, Renato	es_CL
Admission date	dc.date.accessioned	2007-05-04T18:54:15Z
Available date	dc.date.available	2007-05-04T18:54:15Z
Publication date	dc.date.issued	2004-07-26
Cita de ítem	dc.identifier.citation	TETRAHEDRON 60 (31): 6585-6591 JUL 26 2004	en
Identifier	dc.identifier.issn	0040-4020
Identifier	dc.identifier.uri	https://repositorio.uchile.cl/handle/2250/118593
Abstract	dc.description.abstract	The global and local electrophilicity indexes have been used to characterize the reactivity pattern of the C=C double bond towards nucleophilic addition reactions. A wide family of molecules including ketones, esters, anhydrides, nitriles and nitrocompounds containing appropriate substitution on the C=C double bond have been classified within an unique scale of reactivity. The predictive capability of the theoretical model is tested against a series of benzylidenemalononitriles and substituted alpha-nitrostilbenes.	en
Lenguage	dc.language.iso	en	en
Publisher	dc.publisher	PERGAMON-ELSEVIER SCIENCE LTD	en
Keywords	dc.subject	DIELS-ALDER REACTIONS	en
Título	dc.title	Reactivity of the carbon-carbon double bond towards nucleophilic additions. A DFT analysis	en
Document type	dc.type	Artículo de revista