Relationship between local electrophilicity and rate coefficients for the hydrolysis of carbenium ions

Author	dc.contributor.author	Aizman, Arie
Author	dc.contributor.author	Contreras Ramos, Renato	es_CL
Author	dc.contributor.author	Pérez López, Patricia	es_CL
Admission date	dc.date.accessioned	2007-05-15T14:11:00Z
Available date	dc.date.available	2007-05-15T14:11:00Z
Publication date	dc.date.issued	2005-01-24
Cita de ítem	dc.identifier.citation	TETRAHEDRON 61 (4): 889-895 JAN 24 2005	en
Identifier	dc.identifier.issn	0040-4020
Identifier	dc.identifier.uri	https://repositorio.uchile.cl/handle/2250/118602
Abstract	dc.description.abstract	The local electrophilicity of a series of 28 carbenium ions has been ranked within a theoretical absolute scale. New substituent constants are introduced to account for the responses of the electrophilicity pattern induced by multiple substitutions at the carbocation site. The model is used to predict rate coefficients ordering in terms of the experimental hierarchy of electrophilicity established for these systems [Minegishi, S.; Mayr, H. J. Am. Chem. Soc. 2003, 125, 286].	en
Lenguage	dc.language.iso	en	en
Publisher	dc.publisher	PERGAMON-ELSEVIER SCIENCE LTD	en
Keywords	dc.subject	REACTIVITY	en
Título	dc.title	Relationship between local electrophilicity and rate coefficients for the hydrolysis of carbenium ions	en
Document type	dc.type	Artículo de revista