Electrophilicity and spin polarization of simple substituted silylenes

Author	dc.contributor.author	Chamorro, Eduardo
Author	dc.contributor.author	Santos, J. C.	es_CL
Author	dc.contributor.author	Escobar, C. A.	es_CL
Author	dc.contributor.author	Pérez López, Patricia	es_CL
Admission date	dc.date.accessioned	2008-03-25T16:52:34Z
Available date	dc.date.available	2008-03-25T16:52:34Z
Publication date	dc.date.issued	2006-11-11
Cita de ítem	dc.identifier.citation	CHEMICAL PHYSICS LETTERS Volume: 431 Issue: 1-3 Pages: 210-215 Published: NOV 11 2006	en
Identifier	dc.identifier.issn	0009-2614
Identifier	dc.identifier.uri	https://repositorio.uchile.cl/handle/2250/118652
Abstract	dc.description.abstract	The philicity indices, omega(N), and omega(+)(S), characterize a charge transfer process occurring at constant spin number, and the spin polarization for a process at constant number of electrons, respectively. These descriptors are explored for a series of substituted C2HSiX silylene isomers (X = F, Cl, Br, H), providing new insights for a comprehensive description of global and local chemical reactivity patterns and halogen substituent effects in these systems.	en
Lenguage	dc.language.iso	en	en
Publisher	dc.publisher	ELSEVIER	en
Keywords	dc.subject	TRIPLET ENERGY SEPARATIONS	en
Título	dc.title	Electrophilicity and spin polarization of simple substituted silylenes	en
Document type	dc.type	Artículo de revista