| Author | dc.contributor.author | Castro, Enrique A. | |
| Author | dc.contributor.author | Campodónico, Paola R. | es_CL |
| Author | dc.contributor.author | Contreras Ramos, Renato | es_CL |
| Author | dc.contributor.author | Fuentealba Rosas, Patricio | es_CL |
| Author | dc.contributor.author | Santos, José G. | es_CL |
| Author | dc.contributor.author | Leis, J. Ramón | es_CL |
| Author | dc.contributor.author | García Río, Luis | es_CL |
| Author | dc.contributor.author | Sáez, José A. | es_CL |
| Author | dc.contributor.author | Domingo, Luis R. | es_CL |
| Admission date | dc.date.accessioned | 2008-12-17T10:34:23Z | |
| Available date | dc.date.available | 2008-12-17T10:34:23Z | |
| Publication date | dc.date.issued | 2006-03-13 | |
| Cita de ítem | dc.identifier.citation | TETRAHEDRON Volume: 62 Issue: 11 Pages: 2555-2562 Published: MAR 13 2006 | en |
| Identifier | dc.identifier.issn | 0040-4020 | |
| Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/118771 | |
| Abstract | dc.description.abstract | The reactions of quinuclidines with phenyl, 4-methylphenyl, and 4-chlorophenyl 2,4-dinitrophenyl carbonates are kinetically evaluated in aqueous solution. The Bronsted-type plots (log k(N) vs pK(a) of quinuclidinium ions) are linear. The magnitude of the slopes and validated theoretical scales of electrophilicity and nucleophilicity confirm the concerted nature of these reactions. | en |
| Lenguage | dc.language.iso | en | en |
| Publisher | dc.publisher | PERGAMON-ELSEVIER SCIENCE LTD | en |
| Keywords | dc.subject | SECONDARY ALICYCLIC AMINES | en |
| Título | dc.title | Experimental and theoretical study on the substitution reactions of aryl 2,4-dinitrophenyl carbonates with quinuclidines | en |
| Document type | dc.type | Artículo de revista | |
