pi-Strain-induced electrophilicity in small cycloalkynes: A DFT analysis of the polar cycloaddition of cyclopentyne towards enol ethers

Author	dc.contributor.author	Domingo, Luis R.
Author	dc.contributor.author	Pérez López, Patricia	es_CL
Author	dc.contributor.author	Contreras Ramos, Renato	es_CL
Admission date	dc.date.accessioned	2009-03-30T16:18:38Z
Available date	dc.date.available	2009-03-30T16:18:38Z
Publication date	dc.date.issued	2006-01-16
Cita de ítem	dc.identifier.citation	EUROPEAN JOURNAL OF ORGANIC CHEMISTRY Issue: 2 Pages: 498-506 Published: JAN 16 2006	en
Identifier	dc.identifier.issn	1434-193X
Identifier	dc.identifier.uri	https://repositorio.uchile.cl/handle/2250/118788
Abstract	dc.description.abstract	Small cycloalkynes possess a pi-strain-induced electrophilicity related to the bending of the C-SP3-C-SP-C-SP bond angle. For cyclopentyne and benzyne, the electrophilicity index defined in the context of density functional theory gives a coherent rationale for the reactivity of these cycloalkynes, which may act as electrophiles in polar cycloaddition. reactions toward enol ethers.	en
Lenguage	dc.language.iso	en	en
Publisher	dc.publisher	WILEY-V C H VERLAG GMBH	en
Keywords	dc.subject	POLARIZABLE CONTINUUM MODEL	en
Título	dc.title	pi-Strain-induced electrophilicity in small cycloalkynes: A DFT analysis of the polar cycloaddition of cyclopentyne towards enol ethers	en
Document type	dc.type	Artículo de revista