| Author | dc.contributor.author | Dreyse, Paulina | |
| Author | dc.contributor.author | Ramírez, Galo | es_CL |
| Author | dc.contributor.author | Riquelme, Andrea | es_CL |
| Author | dc.contributor.author | Isaacs Casanova, Mauricio | es_CL |
| Admission date | dc.date.accessioned | 2009-03-30T16:55:09Z | |
| Available date | dc.date.available | 2009-03-30T16:55:09Z | |
| Publication date | dc.date.issued | 2006-06 | |
| Cita de ítem | dc.identifier.citation | JOURNAL OF THE CHILEAN CHEMICAL SOCIETY Volume: 51 Issue: 2 Pages: 923-926 Published: JUN 2006 | en |
| Identifier | dc.identifier.issn | 0717-9324 | |
| Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/118790 | |
| Abstract | dc.description.abstract | The spectroelectrochemical properties of a conducting polymer derived from Co(II) tetra-3-amino-phenyl-porphyrin,(poly-Co(II)-TAPP) were studied towards the electrochemical reduction of CO2 on ITO Surface. Under inert atmosphere, the results show that the polymer present a stable Co(I) oxidation state only in basic pH while in more acidic solution this Co(I) does not stabilize. Under CO2 atmosphere the reduced polymer forms a stable adduct with no clear electronic localization. The formation and the stability of this adduct could explain the wide distribution of reaction products. | en |
| Lenguage | dc.language.iso | en | en |
| Publisher | dc.publisher | SOCIEDAD CHILENA DE QUIMICA | en |
| Keywords | dc.subject | AZA-MACROCYCLIC COMPLEXES | en |
| Título | dc.title | "Spectroelectrochemical studies on ITO modified electrodes with a conducting cobalt (II)macrocycle film in the electrochemical reduction of CO2'' | en |
| Document type | dc.type | Artículo de revista | |
