Towards an intrinsic nucleofugality scale: The leaving group (LG) ability in CH(3)LG model system

Author	dc.contributor.author	Jaramillo, Paula
Author	dc.contributor.author	Domingo, Luis R.	es_CL
Author	dc.contributor.author	Pérez López, Patricia	es_CL
Admission date	dc.date.accessioned	2009-04-09T17:33:04Z
Available date	dc.date.available	2009-04-09T17:33:04Z
Publication date	dc.date.issued	2006-03-10
Cita de ítem	dc.identifier.citation	CHEMICAL PHYSICS LETTERS Volume: 420 Issue: 1-3 Pages: 95-99 Published: MAR 10 2006	en
Identifier	dc.identifier.issn	0009-2614
Identifier	dc.identifier.uri	https://repositorio.uchile.cl/handle/2250/118811
Abstract	dc.description.abstract	For an important class of organic reactions in which a fragment of the reactants, the leaving group (LG) or nucleofuge (Z), is detached of the substrate bearing the bonding electron pair, the global electrophilicity index of the CH(3)LG system is proposed as a reliable descriptor of the intrinsic nucleofugality of the LG. The model is illustrated by ranking within a unique relative scale, the LG ability of 28 functional groups commonly involved in substitution and elimination reactions in organic chemistry.	en
Lenguage	dc.language.iso	en	en
Publisher	dc.publisher	ELSEVIER	en
Keywords	dc.subject	CARBON DOUBLE-BONDS	en
Título	dc.title	Towards an intrinsic nucleofugality scale: The leaving group (LG) ability in CH(3)LG model system	en
Document type	dc.type	Artículo de revista