| Author | dc.contributor.author | Ruiz León, Domingo | |
| Author | dc.contributor.author | Galdámez Silva, Antonio | es_CL |
| Author | dc.contributor.author | Manríquez Castro, Víctor | es_CL |
| Admission date | dc.date.accessioned | 2010-01-18T12:42:41Z | |
| Available date | dc.date.available | 2010-01-18T12:42:41Z | |
| Publication date | dc.date.issued | 2008-06 | |
| Cita de ítem | dc.identifier.citation | JOURNAL OF THE CHILEAN CHEMICAL SOCIETY, Volume: 53, Issue: 2, Pages: 1477-1479, 2008 | en_US |
| Identifier | dc.identifier.issn | 0717-9324 | |
| Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/118938 | |
| Abstract | dc.description.abstract | The intercalation compounds Li0.43(PEO)2.4(H2O)1.4K0.57BiP2S6 and Li0.38(PEO)2.1(H2O)1.6K0.62SbP2S6 have been synthesized by the insertion of polyethylene
oxide PEO in LiKMP2S6 (M=Bi, Sb), that contained Li+ and K+ exchangeable cations in their interlayer space. The polymer PEO is able to associate interlayer Li+
cation modifying the ionic conductivity of pristine phases. These intercalation compounds constitute a new family of intercalates in the thiophosphate of Bi and Sb
with Polyethylene oxide as guest species. They have been characterized by powder X-ray diffraction, FTIR-Raman, DTA/TGA analysis and electrical conductivity
measurements. The studied nanocomposite shows values of electrical conductivity (σi ) of about 10-6 Ω-1 cm-1 at room temperature. | en_US |
| Patrocinador | dc.description.sponsorship | This work was supported by
FONDECYT grant Nº 1061116 | en_US |
| Lenguage | dc.language.iso | en | en_US |
| Publisher | dc.publisher | SOC CHILENA QUIMICA | en_US |
| Keywords | dc.subject | Intercalation | en_US |
| Título | dc.title | Intercalation of polyethylene oxide in layered thiophosphate of Bi and Sb | |
| Document type | dc.type | Artículo de revista | |
