| Author | dc.contributor.author | Meneses, L. | |
| Author | dc.contributor.author | Araya, A. | es_CL |
| Author | dc.contributor.author | Pilaquinga, F. | es_CL |
| Author | dc.contributor.author | Fuentealba Rosas, Patricio | es_CL |
| Admission date | dc.date.accessioned | 2010-01-28T13:45:49Z | |
| Available date | dc.date.available | 2010-01-28T13:45:49Z | |
| Publication date | dc.date.issued | 2008-07-20 | |
| Cita de ítem | dc.identifier.citation | Chemical Physics Letters, Volume 460, Issues 1-3, Pages 27-30, 2008 | en_US |
| Identifier | dc.identifier.issn | 0009-2614 | |
| Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/118997 | |
| Abstract | dc.description.abstract | The Baeyer–Villiger oxidation of some aldehydes and ketones has been revised by using the electrophilicity
as a descriptor of reactivity. The global electrophilicity index evaluated at the ground state of a series
of aromatic aldehydes and ketones shows a linear relationship with the rp Hammett substituent
constants. The theoretical scale correctly accounts for the electrophilic activation/deactivation effects
promoted by electron withdrawing and electron releasing substituents in these molecules | en_US |
| Patrocinador | dc.description.sponsorship | Work supported by DGA-PUCE Grant D29101 and FONDECYT
Grant 1080184. | en_US |
| Lenguage | dc.language.iso | en | en_US |
| Publisher | dc.publisher | Elsevier B.V | en_US |
| Título | dc.title | Relationship between the electrophilicity and σp Hammett constant in Baeyer–Villiger reactions | en_US |
| Document type | dc.type | Artículo de revista | |
