| Author | dc.contributor.author | Areche Medina, Carlos | |
| Author | dc.contributor.author | San Martín Barrientos, Aurelio | es_CL |
| Author | dc.contributor.author | Rovirosa, Juana | es_CL |
| Author | dc.contributor.author | Muñoz, Marcelo A. | es_CL |
| Author | dc.contributor.author | Hernández Barragán, Angelina | es_CL |
| Author | dc.contributor.author | Bucio, María A. | es_CL |
| Author | dc.contributor.author | Joseph-Nathan, Pedro | es_CL |
| Admission date | dc.date.accessioned | 2010-07-13T14:20:16Z | |
| Available date | dc.date.available | 2010-07-13T14:20:16Z | |
| Publication date | dc.date.issued | 2010 | |
| Cita de ítem | dc.identifier.citation | Journal of Natural Products, 2010, Vol. 73, No. 1, 79–82 | en_US |
| Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/119071 | |
| Abstract | dc.description.abstract | Careful examination of the published NMR data for isoepitaondiol, a meroditerpenoid from Stypopodium flabelliforme,
suggests that its published structure 1 must be revised. On the basis of extensive 1D and 2D NMR studies, we now
propose that structure 2, with a trans-anti-trans-anti-cis arrangement fits isoepitaondiol diacetate. The relative configuration
of 2 was confirmed by single-crystal X-ray diffraction, while the absolute configuration was evidenced by vibrational
circular dichroism in combination with DFT B3LYP/DGDZVP calculations. | en_US |
| Patrocinador | dc.description.sponsorship | Financial support came from the Proyecto Anillo
“ACT-38”, PBCT “PDA-13”, and CONACYT-Mexico Grant No.
61122. | en_US |
| Lenguage | dc.language.iso | en | en_US |
| Título | dc.title | Stereostructure Reassignment and Absolute Configuration of Isoepitaondiol, a Meroditerpenoid from Stypopodium flabelliforme | en_US |
| Document type | dc.type | Artículo de revista | |
