Author | dc.contributor.author | Dreyse, Paulina | |
Author | dc.contributor.author | Isaacs Casanova, Mauricio | es_CL |
Author | dc.contributor.author | Iturriaga-Vásquez, Patricio | es_CL |
Author | dc.contributor.author | Villagra, Diego | es_CL |
Author | dc.contributor.author | Aguirre, María Jesús | es_CL |
Author | dc.contributor.author | Kubiak, Clifford P. | es_CL |
Author | dc.contributor.author | Glover, Starla D. | es_CL |
Author | dc.contributor.author | Goeltz, John C. | es_CL |
Admission date | dc.date.accessioned | 2011-06-03T13:57:56Z | |
Available date | dc.date.available | 2011-06-03T13:57:56Z | |
Publication date | dc.date.issued | 2010-08-13 | |
Cita de ítem | dc.identifier.citation | JOURNAL OF ELECTROANALYTICAL CHEMISTRY, Volume: 648, Issue: 2, Pages: 98-104, 2010 | es_CL |
Identifier | dc.identifier.issn | 1572-6657 | |
Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/119226 | |
General note | dc.description | Artículo de publicación ISI | es_CL |
Abstract | dc.description.abstract | This work describes the preparation of a new tetraruthenated porphyrin and the corresponding polymeric
film. This macromolecule consists of a Ni(II) tetrapyridylporphyrin coordinated to four [Ru(5-
NO2-phen)2Cl]+ moieties. The 5-NO2-phen ligands are reduced at 0.90 V, generating a radical anion that
is able to generate polymeric coatings onto glassy carbon (GC) electrodes. These polymeric films are very
stable in aqueous solutions. The polymeric films are characterized by electrochemistry, infrared spectroelectrochemistry
(IR-SEC) and atomic force microscopy (AFM). | es_CL |
Patrocinador | dc.description.sponsorship | The authors acknowledge: the financial support of Programa
Bicentenario en Ciencia y Tecnología, CONICYT-Banco Mundial,
Anillo ACT-24 Project, Fundación Andes C14060-40 Project and
UTA-4741-10 Project. P.D. acknowledges CONICYT Doctoral and
AT-24080067 Fellowships. P.D. acknowledges the financial support
of MECESUP UCH 0601 international exchange program. | es_CL |
Lenguage | dc.language.iso | en | es_CL |
Publisher | dc.publisher | ELSEVIER SCIENCE | es_CL |
Keywords | dc.subject | 5-NO2-1,10-phenanthroline | es_CL |
Título | dc.title | Electrochemical preparation of conductive films of tetrapyridylporphyrins coordinated to four [Ru(5-NO2-phen)(2)Cl](+) groups | es_CL |
Document type | dc.type | Artículo de revista | |