Author | dc.contributor.author | Aliaga, A. E. | |
Author | dc.contributor.author | Garrido, C. | es_CL |
Author | dc.contributor.author | Leyton, P. | es_CL |
Author | dc.contributor.author | Díaz Fleming, Guillermo | es_CL |
Author | dc.contributor.author | Gómez Jeria, Juan | es_CL |
Author | dc.contributor.author | Aguayo, T. | es_CL |
Author | dc.contributor.author | Clavijo Campos, Ernesto | es_CL |
Author | dc.contributor.author | Campos Vallette, Marcelo | es_CL |
Author | dc.contributor.author | Sánchez Cortés, S. | es_CL |
Admission date | dc.date.accessioned | 2011-09-01T14:24:45Z | |
Available date | dc.date.available | 2011-09-01T14:24:45Z | |
Publication date | dc.date.issued | 2010-01-27 | |
Cita de ítem | dc.identifier.citation | SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, Volume: 76, Issue: 5, Pages: 458-463, 2010 | es_CL |
Identifier | dc.identifier.issn | 1386-1425 | |
Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/119273 | |
General note | dc.description | Artículo de publicación ISI | es_CL |
Abstract | dc.description.abstract | Arginine amino acid (Arg) has been vibrationally studied through its infrared, Raman and surfaceenhanced
Raman scattering (SERS) spectra, and theoretical calculations. Net charge is used to predict
the possibility to obtain the SERS spectrum of Arg in colloidal solution. The interpretation of the SERS
spectral data suggests that the Arg–Ag nanoparticles interaction in a colloidal solution and in the case of
the Arg coated by Ag is mainly verified through the guanidinium moiety. Theoretical calculations performed
by using extended Hückel theory method for a model of Arg interacting with an Ag cluster support
the observed SERS experimental result. | es_CL |
Patrocinador | dc.description.sponsorship | This work was supported by the CSIC-CONICYT project 2007-
145 and Fondecyt projects 1070078, 1085124 and 1090074,
the Ministerio de Educación y Ciencia of Spain project FIS2007-
63065 and the Comunidad de Madrid project S-0505/TIC/0191
MICROSERES. AEA acknowledges project AT-24090050 CONICYT.
GDF acknowledges project from the Universidad de Playa
Ancha. | es_CL |
Lenguage | dc.language.iso | en | es_CL |
Publisher | dc.publisher | PERGAMON-ELSEVIER SCIENCE LTD | es_CL |
Keywords | dc.subject | Arginine | es_CL |
Título | dc.title | SERS and theoretical studies of arginine | es_CL |
Document type | dc.type | Artículo de revista | |