| Author | dc.contributor.author | Díaz Valenzuela, Carlos | es_CL |
| Author | dc.contributor.author | Lavayen, Vladimir | es_CL |
| Author | dc.contributor.author | O’Dwyer, Colm | |
| Admission date | dc.date.accessioned | 2011-09-01T14:30:26Z | |
| Available date | dc.date.available | 2011-09-01T14:30:26Z | |
| Publication date | dc.date.issued | 2010-05-15 | |
| Cita de ítem | dc.identifier.citation | Journal ofSolidStateChemistry, 183, 1595–1603, 2010. | es_CL |
| Identifier | dc.identifier.issn | 0022-4596 | |
| Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/119276 | |
| General note | dc.description | Artículo de publicación ISI | es_CL |
| Abstract | dc.description.abstract | The solid-statepyrolysisoforganometallicderivativesofacyclotriphosphazeneisdemonstratedtobea
new, simpleandversatilesolid-statetemplatingmethodforobtainingsingle-crystalmicro-and
nanocrystalsoftransitionandvalvemetaloxides.Thetechnique,whenappliedtoMo-containing
organometallicsN3P3[OC6H4CH2CN Mo(CO)5]6 and N3P3[OC6H4CH2CN Mo(CO)4 py]6, resultsinstand-
alone andsurface-depositedlamellarMoO3 single crystals,asdeterminedbyelectronandatomicforce
microscopiesandX-raydiffraction.Thesizeandmorphologyoftheresultingcrystalscanbetunedby
the compositionoftheprecursor.X-rayphotoelectronandinfraredspectroscopiesindicatethatthe
depositionofhighlylamellarMoO3 directly onanoxidized(400nmSiO2) surfaceor(100)single-crystal
silicon surfacesyieldsalayereduniphasicsingle-crystalfilmformedbyclusterdiffusiononthesurface
during pyrolysisofthemetal-carbonylderivatives.ForMoO3 in itslayeredform,thisprovidesanew
routetoanimportantintercalationmaterialforhighenergydensitybatterymaterials. | es_CL |
| Patrocinador | dc.description.sponsorship | Financial supportfromFONDECYTGrantnos.1085011,
1095135, 1090683,and1090282isacknowledged.V.L.acknowl-
edges PBCTGrantACT027.Partofthisworkwasconductedunder
the frameworkoftheINSPIREprogramme,fundedbytheIrish
Government’s ProgrammeforResearchinThirdLevelInstitutions,
Cycle 4,NationalDevelopmentPlan2007–2013. | es_CL |
| Lenguage | dc.language.iso | en | es_CL |
| Publisher | dc.publisher | Elsevier Inc. | es_CL |
| Keywords | dc.subject | Nanostructures | es_CL |
| Título | dc.title | Single-crystalmicro/nanostructuresandthinfilmsoflamellarmolybdenum oxide bysolid-statepyrolysisoforganometallicderivativesofa cyclotriphosphazene | es_CL |
| Document type | dc.type | Artículo de revista | |
