Bis[4-bromo-2-(isopropyliminomethyl)-
phenolato]nickel(II), [Ni(CIoH]IBrNO)2], M, =
540.90, triclinic, Pi, a = 8.789 (6), b = 10.203 (7), c = 6.075 (4) A, a=103.92(5), /3=80-23(5), y=
110.21 (5) °, V = 493-9 (6)/~ 3, Z= 1, Dx =
1-818 Mg m -3, A(Mo Ka) = 0-71069 A, br(Mo Ka)
= 5.01 mm-1, F(000) = 272, T = 293 K, R = 0-055
for 1189 unique observed reflections [F > 3or(F)]. The
Ni atom at the symmetry centre is trans-planar coordinated by two N and two O atoms. The intraligand
O--Ni--N angles are 87-6 and 92.4°; the Ni---O and
Ni--N bond lengths are 1.829 and 1.938 A, respectively.