Experimental and theoretical studies of a new donor–acceptor Re(I) complexes using nitropolypyridil ligand. Analysis of the NLO potential response
Author
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Sanhueza, Luis
Author
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Barrera, Mauricio
es_CL
Author
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Crivelli Picco, Irma
es_CL
Admission date
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2014-01-31T16:06:40Z
Available date
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2014-01-31T16:06:40Z
Publication date
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2013
Cita de ítem
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Polyhedron Volume 57, 2 July 2013, Pages 94–104
en_US
Identifier
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DOI: http://dx.doi.org/10.1016/j.poly.2013.04.028
Identifier
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https://repositorio.uchile.cl/handle/2250/119749
General note
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Artículo de publicación ISI
en_US
Abstract
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A series of eight complexes with general structure [ARe(CO)3D]+, (A = NO2phen, NO2dppz; D = TBP, MOP, DMAP, PEPN) were synthesized and characterized by IR, NMR, UV–Vis spectroscopy and cyclic voltammetry. The donor and acceptor capacities, for the series of ligands employed, were measured in terms of two theoretical indexes, such as electrophilicity and orbital softness. It was found that, when the acceptor ligand is NO2phen, an increase of the donor strength on the ligand causes a change in the first oxidation potential and slight change in the stretching frequencies of the NO2 group, but not of the carbonyl group. This behavior is not observed when the acceptor ligand is NO2dppz. The character of the absorption band (MLCT), ILCT, etc.), and the possibility of non linear optics activity of some of the complexes was analyzed. The calculated static hyperpolarizability, β0, employing two different methods, indicates that the most promising complexes are those containing the PEPN ligand; the NLO behavior response is attributed to the enhancement of the non linear response of the PEPN ligand upon coordination to the [Re(CO)3D]+ fragment.
en_US
Patrocinador
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The authors thank Fondecyt of Chile (Project Nos. 1070799 and 1110991).