Solvent Effects on the Amidic Bond: 1H Nuclear Magnetic Resonance Study of Acetamide and JV-Methylacetamide

Author	dc.contributor.author	González Moraga, Guillermo
Author	dc.contributor.author	Chávez, Ivonne	es_CL
Admission date	dc.date.accessioned	2014-06-03T14:44:53Z
Available date	dc.date.available	2014-06-03T14:44:53Z
Publication date	dc.date.issued	1981
Cita de ítem	dc.identifier.citation	J. Chem. Soc, Faraday Trans. 2, 1981, 77, 2231-2236	en_US
Identifier	dc.identifier.uri	https://repositorio.uchile.cl/handle/2250/119794
Abstract	dc.description.abstract	Af-methylacetamide and acetamide has been studied. The chemical shifts at infinite dilution show approximately linear relationships with the donor number of the solvent. In strong donor solvents it is possible to observe the n.m.r. signáis of two non-equivalerit amidic protons in acetamide owing to the eftect of the solvent on C—N rotation. The influence of the solvent on the chemical shifts and line splittings is discussed as well as the concentration effects by considering possible solute-solvent and solute-solute interactions.	en_US
Patrocinador	dc.description.sponsorship	"Servicio de Desarrollo Científico" of the University (Grant Q 546 813 4)	en_US
Lenguage	dc.language.iso	en	en_US
Type of license	dc.rights	Attribution-NonCommercial-NoDerivs 3.0 Chile	*
Link to License	dc.rights.uri	http://creativecommons.org/licenses/by-nc-nd/3.0/cl/	*
Título	dc.title	Solvent Effects on the Amidic Bond: 1H Nuclear Magnetic Resonance Study of Acetamide and JV-Methylacetamide	en_US
Document type	dc.type	Artículo de revista

Except where otherwise noted, this item's license is described as Attribution-NonCommercial-NoDerivs 3.0 Chile