Determination of sulphide in liquid and solid samples by integrated pervaporation-potentiometric detection
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2001-06-12Metadata
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Vallejo, B.
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Determination of sulphide in liquid and solid samples by integrated pervaporation-potentiometric detection
Abstract
A selective dynamic method for the determination of sulphide in Liquid and solid samples based on the integration of hydrogen sulphide pervaporation and potentiometric monitoring of the sulphide in a laboratory-made module has been developed. The analyte was converted into hydrogen sulphide by reaction with an acidic donor stream and accepted into a dilute NaOH solution after pervaporation. The method proposed has a determination range between 0.1-30 mug ml(-1) and 0.3-50 mug g(-1) for liquid and solid samples, respectively, a precision (expressed as relative standard deviation) of 3.1 and 4.3%, respectively, and has been applied to a sulphide quality control standard containing a certified concentration of 10.10 mug ml(-1) with excellent results.
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ANALYTICA CHIMICA ACTA 436(2):301-307
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