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Two isomorphous imidazole (Him) complexes: [MCl2(Him)(2)(H2O)(2)] (M = Co and Ni)

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IconIsomorphous ATRIA, 2003.pdf (126.9Kb)
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2003-10
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Atria Salas, Ana María
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Two isomorphous imidazole (Him) complexes: [MCl2(Him)(2)(H2O)(2)] (M = Co and Ni)
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Author
  • Atria Salas, Ana María;
  • Cortés, P.;
  • Garland, María Teresa;
  • Baggio, Ricardo;
Abstract
The structures of aquadichlorobis(1H-imidazole) cobalt(II), [CoCl2(Him)(2)(H2O)(2)] (Him is 1H-imidazole, C3H4N2), (I), and aquadichlorobis(1H-imidazole) nickel(II), [NiCl2( Him)(2)( H2O)(2)], ( II), are isomorphous and consist of monomers with inversion symmetry. The three monodentate ligands ( imidazole, chlorine and aqua), together with their symmetry equivalents, define almost perfect octahedra. Hydrogen-bonding interactions via the imidazole and aqua H atoms lead to a three-dimensional network.
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URI: https://repositorio.uchile.cl/handle/2250/120805
ISSN: 0108-2701
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ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS 59: M396-M398 Part: 10
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