The stereoselective synthesis of the Werner complex with substoichiometric sugars
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The stereoselective synthesis of the Werner complex with substoichiometric sugars
Abstract
A tetranuclear complex of Co(III) with hydroxo bridges, so-called “Werner Complex”, was synthesized in the presence of several sugars (1-8) with partial
resolution of this complex. The sugars in 10 mol % with respect to Co(III) induce maximum resolution of the Werner complex.
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The authors
acknowledge financial support from the Research Department of “Universidad
de Chile”, Project D.I. 12 03/12-2.
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Journal of the Chilean Chemical Society, vol.53, n.1, pp. 1379-1381, 2008
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