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Bilayer-by-bilayer antiferroelectric ordering in freely suspended films of an achiral polymer-monomer liquid crystal mixture

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2000-01
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Link, D. R.
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Bilayer-by-bilayer antiferroelectric ordering in freely suspended films of an achiral polymer-monomer liquid crystal mixture
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Author
  • Link, D. R.;
  • Clark, N. A.;
  • Ostrovskii, B. I.;
  • Soto Bustamante, Eduardo;
Abstract
Thin freely suspended films of a mixture of an achiral side-chain liquid crystal polymer and its monomer have been studied with depolarized reflected light microscopy. We observe that regions with an odd number of bilayers exhibit a net spontaneous polarization in the tilt plane of the molecules, while regions with an even number of bilayers have no net polarization. These odd-even effects are direct evidence that the tilted smectic bilayers are anticlinic at the polymer backbone and synclinic at bilayer interface and confirm that the phase is bilayer-by-bilayer antiferroelectric.
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URI: https://repositorio.uchile.cl/handle/2250/121202
ISSN: 1063-651X
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PHYSICAL REVIEW E 61 (1): R37-R40
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