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Mixed complexes of cobalt(III) with D-glucosamine and phenanthroline

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1995
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Blasko, Andrei
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Mixed complexes of cobalt(III) with D-glucosamine and phenanthroline
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Author
  • Blasko, Andrei;
  • Bunton, Clifford A.;
  • Bunel Torrealba, Sergio;
  • Moraga, Exequiel;
  • Ibarra, Carmen;
  • Parada Aliste, José;
Abstract
Examination of 1H chemical shifts of a complex of D-glucosamine with bis-phenanthroline cobalt(III)shows that the dominant ∆-complex is formed from α-D-glucosamine. A molecular mechanics simulation of the structure of this complex indicates that the sugar residue is not markedly perturbed by complexation of Co(III) at the 1-alkoxide and 2-amino groups. The circular dichroism spectrum of the complex formed in solution agrees with that of the isolated material.
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URI: https://repositorio.uchile.cl/handle/2250/121265
ISSN: 0366-1644
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Boletín de la Sociedad Chilena de Química 40: 449-454
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