Nanodecoration of single crystals of 5, 11, 17, 23 - tetra - tert- butyl - 25, 27- bis (cyanomethoxy) - 26, 28 - dihydroxycalix [4] arene
Author
dc.contributor.author
Moris, S.
Author
dc.contributor.author
Silva, N.
Author
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Saitz Barría, Claudio
Author
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Jara Vergara, Paul
Author
dc.contributor.author
Chornik, B.
Admission date
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2018-06-05T19:53:39Z
Available date
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2018-06-05T19:53:39Z
Publication date
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2017
Cita de ítem
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J. Chil. Chem. Soc., 62, Nº 4 (2017)
es_ES
Identifier
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0717-9707
Identifier
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https://repositorio.uchile.cl/handle/2250/148605
Abstract
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Single crystals of 1,3-bis(cyanomethoxy)calix[4]arene (1) were grown from Chloroform/Methanol mixture and these were nanodecorated with colloidal gold nanoparticles (AuNps). The single crystals were then characterized by single-crystal X-ray diffraction (XRD) and Scanning Electronic Microscopy (SEM). The nanodecorated crystals were characterized by UV-Visible Absorption Spectroscopy, Transmission Electronic Microscopy (TEM) and X-ray Photoelectron Spectroscopy (XPS). In this work, it is shown that the stabilization of the nanoparticles occurs through of the interactions of these with the nitrile group, maintaining their shape and size.