Nucleophilicity scale for n- and π-nucleophiles
| Author | dc.contributor.author | Jaramillo, Paula | |
| Author | dc.contributor.author | Fuentealba Rosas, Patricio | |
| Author | dc.contributor.author | Pérez, Patricia | |
| Admission date | dc.date.accessioned | 2018-12-20T14:05:50Z | |
| Available date | dc.date.available | 2018-12-20T14:05:50Z | |
| Publication date | dc.date.issued | 2006 | |
| Cita de ítem | dc.identifier.citation | Chemical Physics Letters, Volumen 427, Issue 4-6, 2018, Pages 421-425 | |
| Identifier | dc.identifier.issn | 00092614 | |
| Identifier | dc.identifier.other | 10.1016/j.cplett.2006.06.066 | |
| Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/153779 | |
| Abstract | dc.description.abstract | A recently introduced empirical nucleophilicity index for a series of n- and π-nucleophiles was evaluated. The index is based on the frontier molecular orbital information of the nucleophile and its electrophilic partner. The model is validated against kinetic data of alkenes, phosphanes, phosphites and amines interacting with the corresponding electrophilic partner. The predictive character of this index is tested for some nucleophiles. © 2006 Elsevier B.V. All rights reserved. | |
| Lenguage | dc.language.iso | en | |
| Type of license | dc.rights | Attribution-NonCommercial-NoDerivs 3.0 Chile | |
| Link to License | dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/cl/ | |
| Source | dc.source | Chemical Physics Letters | |
| Keywords | dc.subject | Physics and Astronomy (all) | |
| Keywords | dc.subject | Physical and Theoretical Chemistry | |
| Título | dc.title | Nucleophilicity scale for n- and π-nucleophiles | |
| Document type | dc.type | Artículo de revista | |
| Cataloguer | uchile.catalogador | SCOPUS | |
| Indexation | uchile.index | Artículo de publicación SCOPUS | |
| uchile.cosecha | uchile.cosecha | SI |
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Except where otherwise noted, this item's license is described as Attribution-NonCommercial-NoDerivs 3.0 Chile